Nanoscale Radiation Engineering of Advanced Materials for Potential Biomedical Applications
Closed for Proposals
Project Type
Coordinated Research ProjectProject Code
F23028
CRP
1537
Approved Date
09.09.2008Project Status
ClosedStart Date
12.01.2009Expected End Date
12.01.2013Completed Date
21.05.2013Description
There are critical needs for advanced materials in the area of biomaterial engineering primarily in generating biomaterials of enhanced specific functionalities improved biocompatibility, and minimal natural rejection but with enhanced inter facial adhesion. These can be achieved by introduction of proper functionalities at the nanoscale dimensions and radiation techniques are uniquely suited for such a task due to their favourable characteristics and in most cases, not possible by other methods of synthesis. Accordingly, many of the developing and developed Member States have an interest in creating advanced materials using a wide array of radiation sources and their broad expertise. In order to use the advantages of radiation techniques and address the needs of Member States for producing advanced materials for various health care applications, a CRP has been formulated based on the recommendations of a Consultant's Meeting. The CRP aims to support MS to develop methodologies for the use of radiation in the synthesis, modification, and characterization of nanomaterials - nanogels, nanoparticles, nanovehicles, nanoporous membranes, and surfaces with enhanced biocompatibility for potential biomedical applications, such as cell-sheet engineering and artificial tissue construction; diagnostics and imaging; drug delivery. Additionally, this CRP will facilitate net working between radiation technologists and biomedical scientists for the development of such applications
Objectives
The overall objective of this project was to support MS on the use of radiation in the synthesis, modification, and characterization of advanced materials by nanoscale control of their properties.
Specific Objectives
To develop radiolytic methodologies for synthesis of nanoparticles and nanoporous membranes, as well as to synthesize and modify nanoparticle surfaces by attaching organic ligands.
To fabricate new stimuli-responsive surfaces by radiation induced grafting on the nanoscale for cell-sheet engineering with improved cell-matrix interactions and cell-function control.
To radiation synthesize polymeric, inorganic and hybrid nanocarriers, providing for controlled loading and improved releasing rate of drugs.
Impact
The CRP had very high impact on enhancing the research capabilities of the participating institutions in radiation engineering on the nanoscale, for the preparation/modification of new polymer materials intended for biomedical applications. The following achievements can be highlighted:
- nanogels and nanoparticles based on natural and/or synthetic polymers and proteins were developed by a precise control of the structure, size, shape and functionality;
- a number of developed nanocarriers were tested for drug delivery applications;
- nanoporous membranes were successfully fabricated, functionalized and tested for drug delivery;
- hydrogel-nanoparticle composites were developed for drug release, as drug-eluting coating for medical implant, and as coating with antimicrobial properties;
- multifunctional electrospun nanofiber network was produced and tested as sensor;
- functional thermo-responsive materials for cell sheet engineering have been prepared and successfully tested for culturing a cell monolayer.
Under this CRP several institutions succeeded in starting the transfer of technology to industry. The participants established numerous collaborations and signed relevant agreements between their institutions that will be in effect long after this CRP is completed. Participants have also used additional Agency support under national and regional TC projects to collaborate, and had also applied jointly for additional support of their work to various EU institutions. Additionally, the participants proposed several follow-up activities.
Relevance
The CRP is in line with research and development priorities of participating MS, and they expressed strong commitment for continued work in this area.
CRP Publications
Serbia
scientific conference contribution
2009
KRKLJES, A., KACAREVIC-POPOVIC, Z., NEDELJKOVIC, J., ?Radiolytic synthesis and characterization of thermoresponsive Ag/PNIPA hydrogel nanocomposites“, 2nd International Conference of Physics of Optical Materials and Devices ICOM 2009, Herceg Novi, Montenegro, August 26-31, 2009, Book of Abstract, p.177.
France - Turkey
Patent
2011
BARSBAY, M., GUVEN, O., BESSBOUSSE, H., CLOCHARD, M-C, WADE, T., RAFT-mediated Radiation-induced Grafting of Acrylic acid from Track-etched PVDF Membranes to Develop Polymer Film Electrodes, Patent EP11306648.4 (deposited the 13th of nov. 2011).
Iran
scientific meeting contribution
2012
Dadbin S, Akhavan, A. In Vitro enzymatic degradation of PLA/layered silicate nanocomposites, ISPST2012, Amirkabir University of Technology, Tehran, Iran, 21-25 October 2012
Egypt
Master Degree Thesis
2012
Ahmed E. Swilem, Radiation Synthesis of Nano – scale Materials For Biomedical Applications, Master Degree Thesis, Faculty of Science, Ain Shams University, 2012
India
scientific paper
2010
BISWAL, J., RAMNANI, S. P., SHIROLIKAR, S., SABHARWAL, S., “Seedless synthesis of gold nanorods employing isopropyl radical generated using gamma radiolysis technique”, Int. J. Nanotechnol. 7 (2010) 907.
India
scientific conference contribution
2011
MISRA, N., BISWAL, J., SABHARWAL, S.; Synthesis of polyvinylpyrrolidone stabilized gold nanoparticles by gamma irradiation, NSRP, JNV Univ., Jodhpur, Rajasthan, India, 10-12, March 2011.
Korea, Rep of
scientific paper
2012
Gopalan A., Kyung Ryeol Ko, Se-Hee Lee, Komathi S., Miklos Veres, Kwang-Pill Lee, “Radiation induced preparation of new multifunctional nanobiowebs”, Radiation Physics and Chemistry 81 (2012) 1407–1410
Brazil
scientific conference contribution
2012
Latin American Congress on Biomaterials – Natal, Brazil. (2012) “Radio-induced protein reticulation for biomedical purposes” – Invited Talk – Gustavo H. C. Varca
India
scientific conference contribution
2011
MISRA, N., BISWAL, J. DHAMGAYE, V. LODHA, G. S., SABHARWAL, S.; Synthesis of silver nanoparticles by using synchrotron radiation at INDUS II, ETALAN, TSH, Mumbai, India, 20-21 October 2011.
China
scientific paper
2010
CHEN, Q.D., SHEN, X.H., GAO, H.C., Radiolytic syntheses of nanoparticles in supramolecular assemblies, Adv. Colloid Interface Sci. 159 (2010) 32. (Invited review)
Iran
scientific paper
2011
Dadbin S, Naimian F, Akhavan A. Poly(Lactic acid)layered Silicate nanocomposite films: morphology, mechanical properties and effects of ?-radiation J Appl Polym Sci 2011; 122: 142-149.
Egypt
scientific paper
Hassan A. Abd El-Rehim , Anke Klingner , El-Sayed A. Hegazy, Ashraf A. Hamed, Ahmed E. Swilem, Developing the Potential Ophthalmic Applications of Pilocarpine Entrapped Into Poly(vinylpyrrolidone)/Poly(acrylic acid) (PVP/PAAc) Nanogel Dispersions Prepared By Gamma Radiation, Biomacromolecules, submitted for publication 2012
Italy
scientific paper
2010
Ricca, V. Foderà, D. Giacomazza, M. Leone, G. Spadaro, C. Dispenza “Probing the internal environment of PVP networks generated by irradiation with different sources” Colloid Polym. Sci. 288 (2010) 969 980.
Thailand
scientific meeting contribution
2009
RIMDUSIT, P., PASANPHAN, W.*, “Gamma-ray generated chitosan nanoparticle: systematic preparation study”, The 7th Eco-Energy and Materials Science and Engineering Symposium, Chiangmai, Thailand, 19-22 November 2009, International Proceeding 131-135.
Italy
scientific meeting contribution
2009
Dispenza, M. Ricca, C. Lo Presti, G. Spadaro, A. Blanazs, G. Battaglia “Biocompatible nanostructured hydrogels incorporating polyaniline nanoparticles” Frontiers in Polymer Science Mainz 7-9 June 2009, Germany. P3-58.
Turkey
scientific paper
2011
AKBULUT, M., LAKSHMI, D., WHITCOMBE, M.J., PILETSKA, E., CHIANELLA, I., GüVEN, O., PLETSKY,S., “Microplates with Adaptive Surfaces” ACS Combinatorial Science, 13(2011)646-652.
Serbia
scientific meeting contribution
2012
Krstic, J., Spasojevic, J., Radosavljevic, A., Kacarevic-Popovic, Z. M., ?Gamma irradiation technique for plasmonic nanoengineering of Ag/hydrogels nanocomposites“, The 3rd International Conference On The Physics Of Optical Materials And Devices, Belgrade, Serbia, September 3-6,2012, Proceedings, P2.1-31, 240.
Japan
scientific paper
2010
K. Enomoto, Y. Maekawa, S. Takano, M. Iwasaki and T. Narita, “Electron-beam-induced chromism combined with photo- or thermal reverse reaction for color imaging“, J. Photopolym. Sci. Technol., 23, 217-224 (2010)
Serbia
scientific conference contribution
2010
KRSTIC, J., KRKLJES, A., PERIC-GRUJIC, A., MITRIC, M., KACAREVIC-POPOVIC, Z., ?Hybrid Ag/PVA hydrogel nanocomposites for potentional biomedical application synthesized by gamma irradiation“, X International Conference on Nanostructured Materials NANO 2010, Rome, Italy, September 13-17, 2010, Abstracts book, Poster-Th-98, p.191.
India
scientific paper
2013
Biswal, J., Singh,S., Rath, M. C., Ramnani S. P., Sabharwal, S., ?Synthesis of CdSe quantum dots in PVA matrix by radiolytic methods”, Int. J. Nanotechnol., 7(2010) 1013- 126N. Misra,V. Kumar, L. Borde, L. Varshney, Localized surface plasmon resonance-optical sensors based on radiolytically synthesized silver nanoparticles for estimation of uric acid, Sensors and Actuators B: Chemical, 2013, 178, 371-378.
Malaysia
scientific paper
2012
Hamzah, Y.; Yunus, W.; N.M. Isa, Pertanika J. Sci. & Technol.,2012, 20, 401
Serbia
scientific meeting contribution
KrstiC J., KrkljeS, A., MitriC, M., KaCareviC-PopoviC, Z., “Characterization and swelling kinetics of Ag/PVA hydrogel nanocomposites synthesized by ?-irradiation”, International Workshop on Processing of Nanostructured Ceramics, Polymers, and Composites, Faculty of Technology and Metallurgy, University of Belgrade, Belgrade, Serbia, November 29-30, 2010, Book of Abstracts, Poster-P4, p.48.
Turkey
scientific paper
2009
BARSBAY, M., GüVEN, O., “A Short review of radiation-induced RAFT-mediated Graft Copolymerization” Rad. Phys. Chem., 78(2009)1054-1059.
Thailand
scientific meeting contribution
2009
PASANPHAN, W.*, RIMDUSIT, P., CHOOFONG, S., CHIRACHANCHAI, S., Chirachanchai. “Chitosan nanoparticle formation: systematic condition based on gamma irradiation and chemical modification studies.” The 6th European Conference on Marine Natural Products, Porto, Portugal, 17-24 July 2009
Serbia
scientific conference contribution
2010
KRSTIC, J., KRKLJES, A., KACAREVIC-POPOVIC, Z., ?Swelling Behavior of Ag/PVA hydrogel nancomposite synhesized by .?-irradiation“, 10th International Conference of Fundamental and Applied Aspects of Physical Chemistry, PHYSICAL CHEMISTRY 2010, September 21-24, 2010, Belgrade, Serbia, Proceedings, p.110-112.
Japan
scientific paper
2012
K. Enomoto, S. Takahashi and Y. Maekawa, “Novel Characterization Method for Graft Polymer Structures Chemically Attached on Thermally Stable Polymer Films”, Macromol. Chem. Phys., 213, 72-78 (2012)
Argentina
scientific conference contribution
2009
GRASSELLI, M., BRITOS, C.N., CARBAJAL, M.L., HIDALGO, R., SOTO ESPINOSA, S.L., QUIROGA, F., TRELLES, J.A., SMOLKO, E.E.; Radiation- Induced grafting of porous polymers for biological applications. V Argentine-Chilean Polymer Symposium. VIII Argentine Polymer Symposium. IX Chilean Symposium of Polymer Chemistry and Physical-Chemistry. 18-21 Octubre 2009. Los Cocos, Córdoba, Argentina.
Argentina
scientific conference contribution
2009
SMOLKO, E. E., BRITOS, C.N., CARBAJAL, M.L., HIDALGO, R., SOTO ESPINOZA, S., QUIROGA, F., TRELLES, J.A., GRASSELLI, M.; Radiation-induced grafting of porous polymers for biological applications, Latin American Section of the American Nuclear Society (LAS/ANS) . Symposium on “Integration of Nuclear Technologies in Latin America". Argentina, Jun 23 – 26, 2009.
Japan
scientific paper
2011
S. Hasegawa, S. Takahashi, H. Iwase, S. Koizumi, N. Morishita, T. Narita, M. Ohnuma and Y. Maekawa, “Radiation-induced graft Polymerization of functional monomer into poly(ether ether ketone)film and structure-property analysis of the grafted membrane”, Polymer, 52, 98-106 (2011)
Japan
scientific paper
2010
N. Nunung, T. Yamaki, H. Koshikawa, M. Asano, K. Enomoto, S. Sawada, Y. Maekawa, K.-O. Voss, C. Trautmann and R. Neumann, “Poly(vinylidene fluoride)-based ion track membranes with different pore diameters and shapes: SEM observations and conductometric analysis“, Electrochemistry, 78, 146-149 (2010)
Argentina
scientific conference contribution
2010
QUIROGA F. Y., GRASSELLI M.; Modificación superficial de HDPE con injertos catiónicos para la adsorción de microorganismos. Aplicaciones en el área de biocatálisis. I° Simposio Argentino de los Procesos Biotecnológicos. Rosario, Argentina, 25 November 2010.
Serbia
scientific conference contribution
2010
KACAREVIC-POPOVIC, Z., DRAGASEVIC, M., KRKLJES, A., POPOVIC, S., JOVANOVIC, Z., TOMIC, S., MISKOVIC-STANKOVIC, V., ?On the Use of Radiation Techology for Nanoscale Engineering of Silver/Hydrogel Based Nanocomposites for Potential Biomedical Application“, 2nd International Conference on Drug Discovery and Therapy, Dubai Men‘s College, Dubai, United Arab Emirates, February 1-4, 2010, Abstracts, SL-319, p.117
Hungary
scientific conference contribution
2011
M. Veres, L. Himics, S. Tóth, K.-P. Lee, A. Gopalan, M. Koós: Surface Functionalization of Nanocrystalline Diamond Using Free Radical Polymerization, 22nd European Conference on Diamond, Diamond-like Materials Carbon Nanotubes and Nitrides, 4-8 September, 2011, Garmisch-Paterkirchen, Germany (poster presentation).
Iran
scientific paper
Dadbin S, Naimian F. Poly (lactic acid)/Hydroxyapatite Bio-nanocomposites: Effects of gamma irradiation and composition on crystallinity, mechanical properties, morphology and enzymatic degradation, submitted to Polymer International
argentina
scientific conference contribution
2012
SOTO ESPINOZA, S. L., GRASSELLI, M.; Synthesis and modification of cylindrical and conical nanopores on track-etched membranes, VIII Congreso Iberoamericano en Ciencia y Tecnología de membranas. Salta, Argentina, 24 - 27 April 2012.
Hungary and Korea, Rep of
scientific conference contribution
2011
Gopalan A., Kyung Ryeol Ko, Se-Hee Lee, Komathi S., Miklos Veres, Kwang-Pill Lee, “ Radiation induced preparation of new multifunctional nanobiowebs”, 12th Tihany Symposium on Radiation Chemistry, August 27 – September 1, 2011, Zalakaros, Hungary (poster presentation).
USA
scientific conference contribution
2012
Hoffman, A.S., “Evolution of Biomaterials into the Nano-Era” plenary talk, 10th meeting of the Ionizing Radiation and Polymers (IRaP2012) Symposium, Krakow, Poland, 14-19 October 2012, Book of Abstracts, pp. 16.
Argentina
scientific conference contribution
2011
SANCHEZ, M.L., SOTO ESPINOZA, S.L., QUIROGA, F.Y., CARBAJAL, M.L., GRASSELLI, M.; Procesos de modificación superficial de polímeros mediante radiación gamma, II Workshop de Transferencia de Tecnología en el área de Materiales. Mar del Plata, Argentina. 28 - 30 November 2011
Poland
scientific conference contribution
2009
Bartoszek B, P. Ulanski, J. M. Rosiak; Radioliza impulsowa jako metoda do wyznaczania stalych szybkosci propagacji w polimeryzacji rodnikowej. 52. Zjazd Polskiego Towarzystwa Chemicznego oraz Stowarzyszenia Inzynierów i Techników Przemyslu Chemicznego, Lódz 12-16 September 2009
Serbia
scientific paper
2012
CvetiCanin, J., Koteski, V., BeloseviC-Cavor, J., RadosavljeviC, A., KaCareviC-PopoviC, Z., Trpkov, DJ., ACimoviC, D., RogiC MiladinoviC, Z., CindriC, M., NeSkoviC O., “MALDI TOF and theoretical investigation of silver clusters obtained by gamma irradiation”, Vacuum 89 (2012) 47-52.
Serbia
scientific paper
2011
JOVANOVIC, Z., KRKLJES, A., STOJKOVSKA, J., TOMIC, S., OBRADOVIC, B., MISKOVIC-STANKOVIC, V., KACAREVIC-POPOVIC, Z., “Synthesis and characterization of Ag/PVP hydrogel nanocomposite obtained by in situ radiolytic method”, Rad. Phys. Chem. 80 (2011) 1208-1215.
Brazil-Argentina
scientific conference contribution
2012
10th Ionizing Radiation and Polymer Symposium – Krakow, Poland. (2012) Oral Presentation - “Radio-synthesized papain nanoparticles for biomedical purposes” - Varca, G.H.C; Ferraz, C. C.; Lopes, P; S.; Grasselli, M.; Lug?o, A.B.
Thailand
scientific meeting contribution
2009
CHOOFONG, S., PASANPHAN, W.* “Particle size lowering of chitosan nanosphere by gamma irradiation and chemical modification”, The 7th Eco-Energy and Materials Science and Engineering Symposium, Chiangmai, Thailand, 19-22 November 2009, International Proceeding 125-130.
China
scientific paper
2010
CHEN, Q.D., SHEN, X.H., Formation of mesoporous BaSO4 microspheres with a larger pore size via Ostwald ripening at room temperature, Cryst. Growth Des. 10 (2010) 3838.
Turkey
scientific paper
2012
WALO, M., PRYZBYTNIAK, G., KAVAKLI, A. P., GüVEN, O., “Radiation-induced Graft Polymerization of N-vinyl pyrrolidone onto Segmented Polyurethane Based on Isophorone Diisocyanate”, Rad. Phys. Chem., 82(2012)xxx.
India
scientific paper
2011
BISWAL, J., RAMNANI, S. P., SHIROLIKAR , S., SABHARWAL S., “Synthesis of rectangular plate like gold nanoparticles by insitu generation of seeds by combining both radiation and chemical methods”, Radiat. Phys. Chem. 80 (2011) 44.
India
scientific conference contribution
2012
MISRA, N., BISWAL, J., SABHARWAL, S., VARSHNEY, L.; Colorimetric estimation of trace levels of hydrogen peroxide using radiolytically synthesized Gold nanoparticles, ICWNCN, Delhi University, New Delhi, India, 13-16, March 2012.
France - Turkey
Patent
2011
European Patent 2011DI0057 issued in the names of Haad Besbousse, Travis Wade, Marie-Claude Clochard, Murat Barsbay and Olgun Güven on “RAFT-mediated Radiation-induced Grafting of Acrylic acid from Track-etched PVDF Membranes to Develop Polymer Film Electrodes”
Korea, Rep of
scientific conference contribution
2011
K-P Lee, Se-Hee Lee, S. Komathi, Gopalan A. “ Preparation of Co/Pd alloy particles dispersed multiwalled carbon nanotube supported nanocatalysts via gamma irradiation”, 12th Tihany Symposium on Radiation Chemistry, August 27 – September 1, 2011, Zalakaros, Hungary (poster presentation).
Japan
scientific paper
2010
S. Sawada, A. Suzuki, T. Terai and Y. Maekawa, “TEMPO addition into pre-irradiated fluoropolymers and living-radical graft polymerization of styrene for preparation of polymer electrolyte membranes, “, Radiat. Phys. Chem., 79, 471-478 (2010)
Brazil
scientific paper
2012
OLIANI W.L, PARRA D.F., RIELLA H.G., LIMA L.F.C.P., LUGAO A.B.. Polypropylene nanogel: “Myth or reality”. Radiation Physics and Chemistry, Volume 81, Issue 9, September 2012, Pages 1460-146.
Japan
scientific paper
2011
K. Enomoto, S. Takahashi, T. Yamashita and Y. Maekawa, “Degradation manner of polymer grafts chemically attached on thermally stable polymer films: swelling-Induced detachment of hydrophilic grafts from hydrophobic polymer substrates in aqueous media“, J. Mater. Chem., 21, 9343-9349 (2011)
Brazil
scientific meeting contribution
2012
IAEA Arcal CVIII – S?o Paulo, Brazil. (2012) “Advances in the use of radiation Technology and nanotechnology in tissue engineering” – Invited Talk – “Nanotecnología aplicada a la salud” - Gustavo H.C. Varca
Brazil
scientific conference contribution
2010
9th Ionizing Radiation and Polymer Symposium – Maryland , US. (2010) Oral Presentation - “Gamma Irradiation Effects over papain activity in different media” - Varca, G.H.C; Paiffer, F.; Mathor, M.B.; Kaneko, T.M.; Rogero, S.O.; Lopes, P.S.; Lug?o, A.B.
Poland
scientific meeting contribution
2009
Rokita B., P. Komorowski, P. Ulanski, B. Walkowiak, J. M. Rosiak; Sonolysis of DNA from calf thymus in aqueous solution, 4th European Young Investigators Conference, Collegium Polonicum, Slubice (Poland); 18 - 21 June 2009
India
scientific paper
2010
BISWAL, J., RAMNANI, S. P., TEWARI, R., DEY G, K., SABHARWAL, S., “Short aspect ratio gold nanorods prepared using gamma radiation in the presence of Cetyltrimethyl ammonium bromide (CTAB) as a directing agent”, Radiat. Phys. Chem. 28 (2010) 441.
Serbia
scientific paper
2010
JOVANOVIC, Z., KRKLJES, A., TOMIC, S., MISKOVIC-STANKOVIC, V., POPOVIC, S., DRAGASEVIC, M., KACAREVIC-POPOVIC, Z., “Properties of Ag/PVP Hydrogel Nanocomposite Synthesized In Situ by Gamma Irradiation”, in Trends in Nanophysics: Theory,Experiment and Technology. Eds: Alexandru Aldea, Victor Barsan. Springer-Verlag Berlin Heidelberg, 2010, 315-328.
India
scientific paper
2013
MISRA, N., KUMAR, V., BORDE, L. AND VARSHNEY, L.; Localized surface plasmon resonance-optical sensors based on radiolytically synthesized silver nanoparticles for estimation of uric acid, Sensors and Actuators B: Chemical, 178 (2013), 371-378.
Poland
scientific meeting contribution
2009
Ulanski P., S. Kadlubowski, J.K Jeszka, J.M. Rosiak; Synthesis of nanogels by radiation-induced intramolecular crosslinking of single polymer chains, Workshop on Progress in Bio- and Nanotechnology, Lodz, Poland; 12-14 February 2009
Malaysia
scientific meeting contribution
2010
Rida, W.M.Z.W. Yunus, Y. Hamzah, K.Z.M. Dahlan, M.H. Mahmood, “Radiation Synthesis Of Micro-Nano Particle Of Acrylated Palm Oil”, Fundamental Science Congress, Universiti Putra Malaysia, Serdang, Malaysia, Oral presentation, May 2010.
Brazil
scientific paper
2012
ALC?NTARA M.T.S.,. BRANT A.J.C, GIANNINI D.R., PESSOA J.O.C.P., ANDRADE A.B., RIELLA H.G.,. LUGAO A.B. Influence of dissolution processing of PVA blends on the characteristics of their hydrogels synthesized by radiation—Part I: Gel fraction, swelling, and mechanical propertiesRadiation Physics and Chemistry, Volume 81, Issue 9, September 2012, Pages 1465-1470.
Japan
scientific paper
2011
T. Yamaki, N. Nunung, H. Koshikawa, M. Asano, S. Sawada, S. Hasegawa, Y. Maekawa, K.-O. Voss, C. Trautmann and R. Neumann, “Conductometric Analysis for the Formation of Poly(vinylidene fluoride)-Based Ion Track Membranes”, ECS Trans., 35, 1-12 (2011)
Argentina
scientific conference contribution
2012
CASAJúS, G., SOTO ESPINOZA, S. L. SMOLKO E.E. GRASSELLI, M.; Síntesis de nanopartículas de proteína mediante radiación ionizante de 60Co, XII Encuentro Superficie y Materiales Nanoestructurados. La Falda, Argentina, 16 - 18 May 2012.
Egypt
scientific paper
Hassan A. Abd El-Rehim , El-Sayed A. Hegazy , Ashraf A. Hamed , Ahmed E. Swilem, Controlling the Size and Swellability of Stimuli-Responsive Poly(vinylpyrrolidone)/Poly(acrylic acid) (PVP/PAAc) Nanogels Synthesized by Gamma Radiation-Induced Template Polymerization, European Polymer Journal, Submitted for publication (2012).
Serbia
scientific paper
2010
CVETICANIN, J., KRKLJES, A., KACAREVIC-POPOVIC, Z., MITRIC, M., RAKOCEVIC, Z., TRPKOV, DJ., NESKOVIC, O., “Functionalization of carbon nanotubes with silver clusters”, Appl. Surf. Sci. 256 (2010) 7048-7055.
India
scientific conference contribution
2013
FRANCIS, S., NUWAD, J., GUPTA, A., SAINIS, J. K., MITRA, D., VARSHNEY , L.; Gamma radiolytic synthesis of gold nanoplates in presence of polydiallyldimethylammoniumchloride as the capping agent NSRP, Meghalaya, India. 20-22, March 2013.
France - Argentina
scientific paper
Soto Espinoza, S. L., Arbeitman, C. R., Clochard, M.C., Grasselli M., Functionalization of nanochannels by radiation-induced grafting polymerization on PET track-etched membranes, Rad. Phys. Chem. (submitted).
Thailand
scientific paper
PASANPHAN, W., CHOOFONG, S., RIMDUSIT, P., “Deoxycholate-chitosan nanosphere fabricated by g-irradiation and chemical modification: nanoscale synthesis and controlling studies”, J. Appl. Polym. Sci. (2010) Revision.
Thailand
scientific paper
2010
PASANPHAN, W.*, RIMDUSIT, P., CHOOFONG, S., PIROONPAN, T., NILSUWANKOSIT, S., “Systematic fabrication of chitosan nanoparticle by gamma irradiation”, Radiat. Phys. Chem., 79 (2010) 1095–1102.
Serbia
scientific meeting contribution
2011
KrstiC, J., SpasojeviC, J., KrkljeS, A., KaCareviC-PopoviC, Z., “Swelling kinetics and antimicrobial activity of radiolytically synthesized nano-Ag/PVA hydrogels”, 12th Tihany Symposium on Radiation Chemistry, Zalakaros, Hungary, August 27 - September 1, 2011, Program and Abstracts, p.110.
Argentina
scientific paper
Soto Espinoza, S. L., Arbeitman, C. R., Clochard, M.C and Grasselli M.; Functionalization of nanochannels by radiation-induced grafting polymerization on PET track-etched membranes, Radiat. Phys. Chem. (submitted for publication)
Serbia
scientific paper
2010
KACAREVIC-POPOVIC, Z., DRAGASEVIC, M., KRKLJES, A., POPOVIC, S., JOVANOVIC, Z., TOMIC, S., MISKOVIC-STANKOVIC, V., “On the Use of Radiation Technology for Nanoscale Engineering of Silver/Hydrogel Based Nanocomposites for Potential Biomedical Application”, The Open Conference Proceedings Journal 1 (2010) 200-206.
Hungary
scientific conference contribution
2012
M. Veres, L. Himics, S. Tóth, K.-P. Lee, A.I. Gopalan, M. Koós, Nanodiamond-Polymer Composites Prepared by Gamma Radiation Initiated Free Radical Polymerization, International Conference on Diamond and Carbon Materials, 3-6 September, 2012, Granada, Spain (poster presentation).
India
scientific paper
2012
MISRA, N., BISWAL, J., GUPTA, A., SAINIS J, K.,. SABHARWAL, S., “Gamma radiation induced synthesis of gold nanoparticles in aqueous polyvinyl pyrrolidone solution and its application for hydrogen peroxide estimation” Radiat. Phys. Chem. 81 (2012) 195.
Italy
scientific paper
2010
Dispenza, M. Ricca, C. LoPresti, G Battaglia, M. La Valle, D. Giacomazza, D. Bulone “E-beam irradation and UV photocrosslinking of microemulsion-laden poly(N-vinyl-2-pyrrolidone) hydrogels for “in-situ” encapsulation of volatile hydrophobic compounds”, Polymer Chemistry, (2010) DOI: 10.1039/c0py00161a.
Korea, Rep of
scientific paper
2012
K-P Lee, Se-Hee Lee, S. Komathi, Gopalan A. “ Preparation of Co/Pd alloy particles dispersed multiwalled carbon nanotube supported nanocatalysts via gamma irradiation” Radiation Physics and Chemistry 81 (2012) 1422–1425
Iran
scientific meeting contribution
2012
Dadbin S, Ahmadian V. Crystallinity of PLA/HAP nanocomposites: effect of gamma irradiation, ISPST2012, Amirkabir University of Technology, Tehran, Iran, 21-25 October 2012
Serbia
scientific paper
2012
Jovanovic, Z., Radosavljevic, A., Siljegovic, M., Bibic, N., Miskovic-Stankovic V., Kacarevic-Popovic, Z., “Structural and optical characteristics of silver/poly(N-vinyl-2-pyrrolidone) nanosystems synthesized by ?-irradiation”, Rad. Phys. Chem. 81 (2012) 1720-1728.
Serbia
scientific meeting contribution
2012
Spasojevic, J., Krstic, J., Radosavljevic, A., Kalagasidis-Krucsic, M., Kacarevic-Popovic, Z., ?Poly(NiPAAm-co-IA) hydrogels synthesized by g-irradiation: Swelling behavior in water“, 11th International Conference on Fundamental and Applied Aspects of Physical Chemistry, PHYSICAL CHEMISTRY 2012, Belgrade, Serbia, Septembar 24-28,2012, Proceedings, Volume II, J-12-P, 550-552.
Serbia
scientific conference contribution
2009
KRKLJES, A., KACAREVIC-POPOVIC, Z., NEDELJKOVIC, J., ?The Influence of Network Parameters on the Properties of Thermoresponsive Ag/PNIPA Hydrogel Nanocomposite Synthesized by Gamma Irradiation“, 11th Annual Conference YUCOMAT 2009, Herceg Novi, Montenegro, August 31 - September 4, 2009, Programme and The Book of Abstracts, P.S.D.9, p.176.
Italy
scientific conference contribution
2009
Dispenza, G. Spadaro “Nuovi materiali nanocompositi a base di idrogeli e polimeri conduttori per l’elettronica molecolare” III Workshop nazionale AICING, Genova 14-16 giugno 2009. K3 (Keynote).
Turkey
scientific paper
2010
ATES, Z., GüVEN, O., Radiation-induced Molecular Imprinting of D-glucose ontoPoly(2-hydroxyethyl methacrylate) Matrices Using various Crosslinking Agents, Rad. Phys. Chem, 79(2010)219-222.
Malaysia
scientific paper
2012
Hamzah, Y.; Yunus, W.; N.M. Isa,; Tajau R,; Hashim, K. e-Polymers, 2012, no. 045.
India
scientific conference contribution
2012
FRANCIS, S. TEWARI, R. MITRA, D. VARSHNEY, L.; Gold nanoplate synthesis by hydrogen peroxide reduction of gold chloride, ISMC, Mumbai, India, 11-15, December 2012.
Japan
scientific paper
2011
H. Iwase, S. Sawada, T. Yamaki, Y. Maekawa and S. Koizumi, “Preirradiation graft polymerization of styrene in a poly(tetrafluoroethylene) film, investigated by time-resolved small-angle neutron scattering “, Int. J. Polym. Sci., 2011, 301807 (2011).
Brazil
scientific paper
2012
OLIVEIRA M.J.A., AMATO V.S., LUGAO A.B., PARRA D.F.. Hybrid hydrogels produced by ionizing radiation technique. Radiation Physics and Chemistry, Volume 81, Issue 9, September 2012, Pages 1471-1474.
Iran
scientific paper
2013
DIBA BEHNOODFAR1, SUSAN DADBIN2, and MASOUD FROUNCHI, PLA Microspheres-Embedded PVA Hydrogels Prepared by Gamma-irradiation and Freeze-Thaw Methods as Drug Release Carriers, International Journal of Polymeric Materials 2013, 62, 28-33.
China
scientific paper
2010
YANG, S.G., CHEN, Q.D., SHI, J.F., SHEN, X.H., Controllable radiolytic reduction of Cu2+ in aqueous solution by ?-cyclodextrin, Acta Phys.-Chim. Sin. 26 (2010) 805. (in Chinese)
Malaysia
scientific paper
2011
Tajau, R. J. Nuc. And Rel. Tech., 2011, 8, 6.
Argentina
scientific conference contribution
2012
QUIROGA F. Y., GRASSELLI, M.; Síntesis y caracterización de una red catiónica injertada en HDPE para promover la adsorción de microrganismos, XII Encuentro Superficie y Materiales Nanoestructurados. La Falda, Argentina, 16 - 18 May 2012.
Poland
scientific meeting contribution
2009
Ulanski P.; Radiation chemistry of polymers - some opportunities and trends, Radiation Chemistry in the 21st Century A Visionary Meeting, University of Notre Dame, Notre Dame,Indiana, USA, 12 – 15 July 2009
Poland
scientific meeting contribution
2009
Rokita B., P. Komorowski, P. Ulanski, B.Walkowiak, J.M. Rosiak; Wplyw ultradzwieków na kwas deoksyrybonukleinowy - DNA, 52. Zjazd Polskiego Towarzystwa Chemicznego oraz Stowarzyszenia Inzynierów i Techników Przemyslu Chemicznego, Lódz 12-16 September 2009
Turkey
scientific paper
2009
BARSBAY, M., GüVEN, O., DAVIS, T. P., BARNER-KOWOLLIK, C., BARNER, L., “RAFT-mediated polymerization and grafting of 4-styrenesulfonate from cellulose initiated via gamma-radiation” Polymer, 50(2009)973-982.
Argentina
scientific paper
2012
Soto Espinoza, S. L., Sánchez, M. L., Risso, V., Smolko, E. E. and Grasselli M.; Radiation Synthesis of Seroalbumin Nanoparticles, Radiat. Phys. Chem. 81 (2012) 1417–1421.
Poland
scientific conference contribution
2009
Bartoszek N, P. Ulanski, J. M. Rosiak; Free-radical reactions involving macromolecules as studied by pulse radiolysis - factors influencing reaction rate constants, 4th European Young Investigators Conference, Collegium Polonicum, Slubice (Poland); 18 - 21 June 2009
Poland
scientific meeting contribution
2009
Kadlubowski S, R. Czechowska-Biskup, P. Ulanski, J. M. Rosiak; Inicjowana radiacyjnie synteza nanozeli polimerowych, III Krajowa Konferencja Nanotechnologii - nano2009, Warszawa (Poland); 22-26 June 2009
Iran
scientific meeting contribution
2012
Dadbin S, Naimian F. Kheirkhah Y. PLA/clay nanocomposites: Effects of preparation method on morphology and mechanical properties, ISPST2012, Amirkabir University of Technology, Tehran, Iran, 21-25 October 2012
Japan
scientific paper
2012
K. Enomoto, S. Takahashi, R. Rohani, Y. Maekawa, “Synthesis of Copolymer Grafts Containing Sulfoalkyl and Hydrophilic Groups in Polymer Electrolyte Membranes”, J. Membr. Sci., 415–416, 36–41 (2012)
Argentina
scientific conference contribution
2011
QUIROGA F. Y., GRASSELLI M.; Analysis of surface cationic microhydrogel structures by in situ fluorescence detection. 3rd South American Workshop & International Gregorio Weber Conference and Workshop on advance fluorescence techniques, Buenos Aires, Argentina, 12 - 17 December 2011.
Serbia
scientific conference contribution
2010
CVETICANIN, J., KRKLJES, A., KACAREVIC-POPOVIC, Z., TRPKOV, DJ., CINDRIC, M., NESKOVIC, O., ?Mass Spectrometric Investigation of Silver Clusters“, 10th International Conference of Fundamental and Applied Aspects of Physical Chemistry, PHYSICAL CHEMISTRY 2010, September 21-24, 2010, Belgrade, Serbia, Proceedings, p.60-62.
Brazil
scientific paper
2010
MOMESSO R G.R.A., MORENO C.S., ROGERO S.O., ROGERO J.R., SPENCER P.J.,LUGAO A.B. Radiation stability of resveratrol in immobilization on poly vinyl pyrrolidone hydrogel dressing for dermatological use. Radiation Physics and Chemistry, Volume 79, Issue 3, March 2010, Pages 283-285
Italy
scientific conference contribution
2009
Dispenza, M.A. Sabatino, A. Niconov, E. Caponetti, R. Matassa, G. Navarra, S. Piazza, G. Spadaro “Biocompatible polyaniline nanocomposites build a soft interface between biology and opto-electronics” Polymerfest, Palermo August 30 – September 02, 2009. P 223-224
Japan
scientific paper
2010
S. Sawada, T. Yamaki, T. Ozawa, A. Suzuki, T. Terai, and Y. Maekawa, “Structural analysis of radiation-grafted polymer electrolyte membranes by dissipative particle dynamics simulation”, Kobunshi Ronbunshu, 67, 224-227(2010) (in Japanese)
India
scientific conference contribution
2012
KUMAR,V., GOEL, N. K., FRANCIS, S., BHARDWAJ, Y. K., VARSHNEY, L.; Hybrid Organic/Inorganic nanocomposite coating by electron beam curing process, Thermans, Mumbai, India, 31st January-2nd February 2012.
Japan
scientific paper
2011
S. Sawada and Y. Maekawa, “Proton Conduction Characteristics in Radiation-Grafted Polymer Electrolyte Membranes Based on Perfluorinated and Aromatic Hydrocarbon Polymers”, ECS Trans., 41, 2125-2133 (2011)
India
scientific conference contribution
2012
MISRA, N., KUMAR, V., VARSHNEY, L.; Silver nanoparticles based optical biosensors for estimation of uric acid, ISMC, TSH, Mumbai, India, 11-15 December 2012, (Best Poster Award).
Serbia
scientific meeting contribution
2011
Spasojevic, J., Krstic, J., Radosavljevic, A., Kalagasidis-Krusic, M., Kacarevic-Popovic, Z., “Thermoresponsive silver/poly(N-isopropylacrylamide) hydrogel nanocomposites synthesized by gamma irradiation”, Tenth Young Researchers Conference - Materials Science and Engineering, Serbian Academy of Sciences and Arts (SASA), Belgrade, Serbia, December 21-23, 2011, Program and the Book of Abstracts, XI/2, p.44
Malaysia
scientific paper
2012
Tajau, R. Adv. Mat. Res., 2012, 364, 278.
Argentina
scientific conference contribution
2012
SOTO ESPINOZA, S. L., GRASSELLI, M.; Análisis fluorométrico de nanoinjertos en membranas de poros perfectos, Encuentro Superficie y Materiales Nanoestructurados. La Falda, Argentina, 16 - 18 de May 2012.
Serbia
scientific meeting contribution
2012
Krstic, J., Spasojevic, J., Radosavljevic, A., Kacarevic-Popovic, Z., ?Non-isothermal kinetics of dehydratation of Ag/PVA hydrogel nanocomposite synthesized by g-irradiation“, 11th International Conference on Fundamental and Applied Aspects of Physical Chemistry, PHYSICAL CHEMISTRY 2012, Belgrade, Serbia, Septembar 24-28, 2012, Proceedings, Volume I, C-20-P, 212-214.
France - Turkey
scientific paper
BARSBAY, M., GUVEN, O., BESSBOUSSE, H., WADE, T.L., CLOCHARD M-C., Nanopore size tuning of polymeric membranes using the RAFT-mediated radical polymerization, J. Memb. Sci. (submitted)
Hungary
scientific conference contribution
2012
B. Beiler, M. Veres, L. Himics, M. Koós and á. Sáfrány: Raman Spectroscopic Study on Porous Polymer Monoliths Prepared by Radiation Initiated Polymerization, 12th Tihany Symposium on Radiation Chemistry, August 27 – September 1, 2011, Zalakaros, Hungary (poster presentation).
Japan
scientific paper
2010
J. Chen, D. Li, H. Koshikawa, M. Asano, and Y. Maekawa, “Crosslinking and grafting of polyetheretherketone film by radiation techniques for application in fuel cells”, J. Membr. Sci., 362, 488-494 (2010)
Brazil
scientific meeting contribution
2012
Sistemas avanzados de administración de medicamentos - Instituto de Ciencias Nucleares, UNAM, Mexico City, Mexico. (2012) Invited Talk “Computational tools applied to the development of protein-based drug carriers” – Gustavo H. C. Varca
Italy
scientific conference contribution
2009
Dispenza, M.A. Sabatino, D. Bulone, D. Giacomazza, G. Ghersi, M. Leone, S. Rigogliuso, G. Spadaro “Macromolecular engineering of hydrogels: from macro to nano scalar materials for different levels of biointeraction” Polymerfest, Palermo August 30 – September 02, 2009, p 237-238.
Argentina
scientific conference contribution
2011
QUIROGA F. Y., LELES DA SOUZA, A., LAMEIRAS F.S., GRASSELLI M.; Microhidrogeles catiónicos injertados sobre HDPE : síntesis, caracterización físicoquímica y estudios funcionales en la adsorción de Escherichia coli. XL Reunión Anual de la Sociedad Argentina de Biofísica. Buenos Aires, Argentina, 5 – 7 December 2011
Brazil
scientific conference contribution
2012
International Conference on Protein Stabilization – Prostab2012 Lisbon, Portugal. (2012) Oral presentation - “ Stabilization of Papain by cyclic oligosaccharides: influence of B-CD and B-derivatives over the biological properties of papain” - Varca, G.H.C; Ferraz, C.C; Esteves-Pedro, N.M.; Lopes, P.S.; Mathor, M.B.; Lug?o, A.B.