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          Radiation Curing of Composites for Enhancing their Features and Utility in Health Care and Industry

          Closed for Proposals

          Project Type

          Coordinated Research Project

          Project Code

          F22051

          CRP

          1783

          Approved Date

          15 November 2010

          Project Status

          Closed

          Start Date

          14 March 2011

          Expected End Date

          14 March 2015

          Completed Date

          3 November 2015

          Description

          Composite materials combine properties of the individual components in a synergetic manner to produce a variety of materials in an efficient and cost effective manner. Thus, composite materials today are being used in various applications from sports equipment, automotive and aerospace industries to food packaging and artificial organs. Materials reinforced with nanoscale components are adding new dimensions to composite materials and enable further major improvements in functional and structural properties. The incorporation of only a few percent of nano-sized particles can make dramatic property changes that may result in sensing, actualization or self-healing properties of the resulting composite. Several major issues need to be addressed to utilize the full potential of such nanofillers, and among them: (i) incompatibility or weak interfacial bonding between the matrix and the nanoscale component, and (ii) agglomeration of nanosized component during processing resulting in inhomogeneous distribution. According to the results of ongoing investigation and products preparation in several Member States institutions, radiation technology offers a way of overcoming these challenges by grafting of appropriate monomers/polymers onto the nanofiller surface thereby fixing their morphology and at the same time making them compatible with the host polymer. Additionally, radiation techniques offer the possibility for simultaneous synthesis of the nanoparticle component and crosslinking of the matrix of the composite that is not possible to achieve by other techniques. With the availability of lower cost self-shielded low energy electron beam accelerators, this process is increasingly becoming available for developing member states. In order to use the advantages of radiation techniques and address the needs of Member States for producing advanced composite materials, this CRP has been formulated based on the recommendations of a Consultant’s Meeting. The CRP aims to support MS to develop methodologies and protocols for new abrasion resistant coating formulations, radiation curable nano-composites from natural polymers, new biodegradable packaging materials suitable for radiation sterilization, and new methods to modify surface characteristic of nano-sized materials to enhance polymer fillers interaction. This CRP will provide a forum for knowledge and technology transfer among the participating institutions, as well as to promote early involvement of developing countries in knowledge-intensive R&D programs to enhance their level of competence and confidence and promote the local spin-off initiatives.

          Objectives

          To enhance member States capability in the use of radiation technology for production of nano-composites with enhanced quality, safety, stability and functionality for advanced applications.

          Specific Objectives

          To assess the methods to modify surface characteristic of nano-sized materials to enhance polymer fillers interaction

          To develop radiation curable nano-composites from natural polymers

          To harmonize preparations and specifications of new biodegradable packaging materials suitable for radiation sterilization

          To standardize formulations of new scratch and abrasion resistant coatings with enhanced surface finishing

          Impact

          The participants have developed numerous protocols for the preparation of nanocomposites that would not have been there without the joint effort under this CRP, and which are being transferred into new products. New preparation methods have been discovered that resulted in improved characteristics of the final products enabling new applications. Besides the collaboration towards the objectives of the CRP, strong collaboration and a network had been established that is in place and under a strategic partnership projects within the framework of EU Erasmus program is organizing and delivering training and teaching programme in enhancing development and transfer of knowledge of application of ionizing radiation in materials processing. The CRP also had an impact on the new CRP entitled: Application of Radiation Technology for the Development of Advanced Packaging Materials for Food Products", which benefits from the packaging materials developed under this completed CRP. Additionally, the journal articles published under this CRP enriched the knowledge of the scientific community worldwide.

          Relevance

          The CRP in line with the objective of the project 2.5.2.2, to enhance Member State capabilities in applying radiation technology for advanced materials development and processing natural polymers into value added products, and it is relevant to Member States programmes and projects.

          CRP Publications

          Canada
          International scientific journal
          2012
          Akter, N., Khan, R., Salmieri, S., Sharmin, N., Dussault, D., Lacroix, M. Fabrication and mechanical characterization of biodegradable and synthetic polymeric films: Effect of ?-irradiation. Rad. Phys. Chem., 81 (2012) 995-998.
          Canada/Egypt
          International scientific journal
          2010
          Senna M.M., Salmieri S, El-Naggar AW, Safrany A, Lacroix M. Improving the compatibility of Zein / Polyvinyl alcohol blends by gamma irradiation and graft copolymerization of acrylic acid. J. Agric. Food Chem., 58 (2010) 4470-4476.
          India
          International scientific journal
          2014
          CHAUDHARI, C. V., K. A. DUBEY, Y. K. BHARDWAJ AND S. SABHARWAL, Radiation processed styrene-butadiene rubber/ethylene-propylene diene rubber/multiple-walled carbon nanotubes nanocomposites: Effect of MWNT addition on solvent permeability behavior, Journal of Macromolecular Science, Part B: Physics 51(5)(2014) 839-859
          Pakistan
          International scientific journal
          2013
          YASIN, T., NISAR, M., SHAFIQ, M., NHO, Y.C., AHMAD, R. “Influence of Sepiolite and Electron Beam Irradiation on the Structural and Physicochemical Properties of Polyethylene/Starch Nanocomposites”. Polym. Composites, 34/3 (2013) 408–416.
          india
          International scientific journal
          2014
          MAJJI, S., K. A. DUBEY, R. K. MONDAL, Y. K. BHARDWAJ AND S. ACHARYA, Development of Electron Beam Cross-Linked PDMS/PTFEM Composites with Low Coefficient of Friction and High Elastic Modulus, Polymer - Plastics Technology and Engineering 53(5) (2014) 435-441.
          Turkey
          International scientific journal
          2014
          BAKAR, A., GüVEN,O., ZEZIN, A.A., FELDMAN,V.I., “Controlling the size and distribution of copper nanoparticles in double and triple polymer-metal complexes by X-ray irradiation” Rad. Phys. Chem.,94(2014)62-65.
          USA/France
          International scientific journal
          2014
          FARAHANI,.M., CLOCHARD, M.C., GIFFORD, I., BARKATT, A. AND AL-SHEIKHLY, M., Differences in Fundamental Reaction Mechanisms between High and Low-LET in Recent Advancements and Applications of Ionizing Radiation, Rad. Phys. Chem., 105 (2014) 39–47.
          Canada
          International scientific journal
          2013
          Khan, R.A., Beck, S., Dussault, D., Salmieri, S., Bouchard, J., Lacroix, M. Mechanical and barrier properties of nanocrystalline cellulose reinforced poly (caprolactone) composites: effect of gamma radiation. J. Appl. Polymer Sc., 129 (2013) 3038-3046.
          Canada
          International scientific journal
          2012
          Khan, R., Dussault D., Salmieri, S., Safrany, A., Lacroix, M., Improvement of the mechanical and barrier properties of methylcellulose-based films by treatment with HEMA and silane monomers under gamma radiation. Rad. Phys. Chem., 81 (2012) 927-931.
          Serbia
          International scientific journal
          2014
          KRSTIC, J., SPASOJEVIC, J., RADOSAVLJEVIC, A., PERIC-GRUJIC, A., DJURIC, M., KACAREVIC-POPOVIC, Z., POPOVIC, S., In vitro silver ion release kinetics from nanosilver/poly(vinyl alcohol) hydrogels synthesized by gamma irradiation, J. Appl. Polym. Sci. 131 (2014) Article No. 40321.
          India
          International scientific journal
          2013
          SINHA, S. K., K. A. DUBEY, V. GROVER, P. SASTRY, Y. K. BHARDWAJ, L. PANICKER, A. K. TYAGI, P. A. MAHANWAR AND V. A. BAMBOLE, Selective interfacial localization in conducting polycaprolactam/ethylene vinyl acetate/carbon black composites, Polymer Composites 34(6) (2013) 912-919.
          Canada
          International scientific journal
          2012
          Khan, R., Salmieri, S., Dussault, D., Uribe-Calderon, J., Kamal, M.R., Safrany, A., Lacroix, M. Preparation, gamma-irradiation and thermo-mechanical characterization of chitosan loaded methylcellulose films. J. Polym. Environ. 20 (2012) 43-52
          Canada
          International scientific journal
          2012
          Sharmin, N., Khan, R., Dussault, D., Salmieri, S., Akter, N., Lacroix, M. Effectiveness of silane monomer and gamma radiation on chitosan films and PCL-based composites. Rad. Phys. Chem., 81 (2012) 932-935.
          Canada
          International scientific journal
          2012
          Huq, T., Khan, A., Dussault, D., Salmieri, S., Khan, R.A., Lacroix, M. Effect of ?-irradiation on the physico-chemical properties of alginate-based films and beads. Rad. Phys. Chem. 81 (2012) 945-48.
          Canada
          International scientific journal
          2014
          Lacroix, M., Khan, R., Senna, M., Sharmin, N., Salmieri, S., SAFRANY, A, Radiation grafting on natural films. Rad. Phys. Chem., 94 (2014) 88-92.
          Germany
          International scientific journal
          2014
          BAUER, F., DECKER, U., NAUMOV, S., RIEDEL, C. (2014). Photoinitiator-free UV curing and matting of acrylate-based nanocomposite coatings: Part 3. Progress in Organic Coatings 77 (2014) 1085-1094.
          Serbia
          International scientific journal
          2014
          KRSTIC, J., SPASOJEVIC, J., RADOSAVLJEVIC, A., SILJEGOVIC, M., KACAREVIC-POPOVIC, Z., Optical and structural properties of radiolytically in situ synthesized silver nanoparticles stabilized by chitosan/poly(vinyl alcohol) blends, Rad. Phys. Chem. 96 (2014) 158-166.
          Italy
          2012
          International scientific journal
          ALESSI S, SPINELLA A, CAPONETTI E, DISPENZA C, SPADARO G. Structural investigation of e-beam cured epoxy resins through solid state NMR. Radiat. Phys. Chem. 81 (2012) 1328-1331.
          Canada
          International scientific journal
          2012
          Sharmin, N., Khan, R.A., Salmieri, S., Dussault, D., Bouchard, J., Lacroix, M. Modification and characterization of biodegradable methylcellulose films with trimethylolpropane trimethacrylate (TMPTMA) by gamma radiation: effect of nanocrystalline cellulose. J. Agric. Food Chem., 60 (2012) 623-629.
          India
          International scientific journal
          2011
          DUBEY, K. A., Y. K. BHARDWAJ, C. V. CHAUDHARI, N. K. GOEL, S. SABHARWAL, K. RAJKUMAR AND S. K. CHAKRABORTY, Radiation effects on styrene-butadiene-ethylene-propylene diene monomer-multiple walled carbon nanotube nanocomposites: Vulcanization and characterization, Polymers for Advanced Technologies, 22(12)(2011)1888-1897.
          Canada
          International scientific journal
          2012
          Sharmin, N., Khan, R., Salmieri, S., Dussault, D., Bouchard, J., Lacroix, M. Mechanical and barrier properties of methylcellulose-based films grafted with trimethylolpropane trimethacrylate by gamma irradiation: effect of filling with cellulose nanocrystals, J. Sc. Technol. For Forest Products and Processes 2 (2012) 24-31.
          Canada
          International scientific journal
          2013
          Khan, R. A., Beck, S., Dussault, D., Salmieri, S., Bouchard, J., Lacroix, M. Mechanical and barrier properties of carbon nanotubes-reinforced PCL-based composite films: effect of gamma radiation. J. Appl. Polym. Sci. 127 (2013) 3962-9.
          France/Vietnam
          International scientific journal
          2014
          VO K. D. N., KOWANDY C., DUPONT L., NGUYEN Q. H., COQUERET X., Radiation synthesis of chitosan-stabilized gold nanoparticles: comparison between e(-) beam and gamma irradiation, Radiat. Phys. Chem. (2014), 94, 84-87
          Canada
          International scientific journal
          2014
          SALMIERI. S., ISLAM, F., KHAN, R. A., HOSSAIN, F. M., IBRAHIM, H. M. M., MIAO, C., HAMAD, W. Y., LACROIX, M., Antimicrobial nanocomposite films made of poly(lactic acid)-cellulose nanocrystals (PLA-CNC) in food applications. Part B: Effect of oregano essential oil release on the inactivation of Listeria monocytogenes in mixed vegetables. Cellulose. (2014) CELS-D-13-00484R2.
          India
          International scientific journal
          2014
          DUBEY, K. A., S. K. SINHA, Y. K. BHARDWAJ, L. PANICKER AND L. VARSHNEY, Carbon Black-Filled PE/PP/EPDM Blends: Phase Selective Localization of Carbon Black and EPDM-Induced Phase Stabilization." Polymer - Plastics Technology and Engineering 53(5) (2014) 442-450.
          Canada
          International scientific journal
          2012
          Khan, A., Huq, T., Khan, R.A., Dussault, D., Salmieri, S., Lacorix, M. Effect of ?-irradiation on the mechanical and barrier properties of HEMA grafted chitosan-based films. Rad. Phys. Chem., 81 (2012) 941-44.
          Pakistan
          International scientific journal
          2013
          KHAN, A., MEHMOOD, S., SHAFIQ, M., YASIN, T., AKHTER, Z., AHMAD, S. “Structural and Antimicrobial Properties of Irradiated Chitosan and its Complexes with Zinc”. Radiat Phys Chem, 91 (2013) 138–142
          Turkey
          International scientific journal
          2013
          KARSLI, N.,G., AYTA?, A., AKBULUT, M., DENIZ, V., GüVEN,O., “Effect of irradiated polypropylene compatibilizer on the properties of short carbon fiber reinforced polypropylene composites” Rad. Phys. Chem.,84(2013)74-78
          Italy
          International scientific journal
          2012
          DISPENZA C, SABATINO MA, NICONOV A, CHMIELEWSKA D, SPADARO G. E-beam crosslinked, biocompatible, functional hydrogels incorporating polyaniline nanoparticles. Radiat. Phys. Chem. 81 (2012) 1456-1459.
          Canada
          International scientific journal
          2010
          Khan, R., Salmieri, S., Dussault, D., Calderon, J.U., Kamal, M.R., Safrany, A., Lacroix, m. Production and Properties of Nanocellulose Reinforced Methylcellulose-Based Biodegradable Films. J. Agric. Food Chem., 58 (2010) 7878-7885
          Poland
          International scientific journal
          2013
          NOWICKI A, G. PRZYBYTNIAK, K. MIRKOWSKI, “Radiacyjne sieciowanie zywic epoksydowych z napelniaczami nanoweglowymi” in ?Modyfikacja polimerów. Stan i perspektywy w roku 2013” Ed. Ryszarda Stellera i Danuty Zuchowskiej, Wroclaw 2013, TEMPO s.c., ISBN 978-83-85520-19-0, p. 382-385.
          Turkey
          International scientific journal
          2012
          BAKAR, A., DE, V.V., ZEZIN, A.A., ABRAMCHUK, S.S., GüVEN,O., FELDMAN,V.I., “Spatial organization of a metal-polymer nanocomposite obtained by radiation-induced reduction of copper ions in the poly(allyl amin)-poly(acrylic acid)-Cu2+ system” Mendeleev Commun., 22(2012)211.
          Malaysia/Germany
          International scientific journal
          2013
          NIK GHAZALI NIK SALLEH, MOHD SOFIAN ALIAS, H-J.GL?SEL & R.MEHNERT. High performance radiation curable hybrid coatings, Radiation Physics and Chemistry Journal, 84 (2013) 70-73.
          Vietnam
          International scientific journal
          2013
          PHU, D.V., TRINH, N.T.A., DU, B.D., HIEN, N.Q., Gamma-irradiation synthesis of silver nanoparticles fixing in porous ceramic for application in water treatment, Vietnam Journal of Chemistry, 51 (2013) 653-657.
          India
          International scientific journal
          2011
          DUBEY, K. A., Y. K. BHARDWAJ, C. V. CHAUDHARI AND S. SABHARWAL, LDPE/EVA/PCR/MWNT nanocomposites: Radiation crosslinking and physicomechanical characteristics, Polymer Composites 32(5) (2011) 737-746
          Italy/Poland
          International scientific journal
          2014
          SPADARO G, ALESSI S, DISPENZA C, SABATINO MA, PITARRESI G, TUMINO D, PRYZBYTNIAK G, Radiation curing of carbon fibre composites. Radiat. Phys. Chem. 94 (2014) 14-17.
          India
          International scientific journal
          2012
          DUBEY, K. A., Y. K. BHARDWAJ, K. RAJKUMAR, L. PANICKER, C. V. CHAUDHARI, S. K. CHAKRABORTY AND S. SABHARWAL, Polychloroprene rubber/ethylene-propylene diene monomer/multiple walled carbon nanotube nanocomposites: Synergistic effects of radiation crosslinking and MWNT addition, Journal of Polymer Research 19(5)(2012).
          Malaysia
          International scientific journal
          2011
          NIK GHAZALI NIK SALLEH, MOHD FIRDAUS YHAYA, AZMAN HASSAN, AZNIZAM ABU BAKAR AND MUNIRAH MOKHTAR, Effect of radiation dosages on the properties of nanocomposite coatings. Radiation Physics and Chemistry Journal 80 (2011) 136-141.
          Vietnam
          International scientific journal
          2013
          QUOC, L.A, PHU, D.V, DUY, N.N, LANG, V.T.K, LAN, N.T.K., TRINH, N.T.A., HIEN, N.Q., Study on antibacterial activity (Escherichia coli) of porous ceramic fixed with silver nanoparticles, Nuclear Science and Technology, VINATOM, 3 (2013) 25-30.
          Italy/Poland
          International scientific journal
          2014
          TODARO S, SABATINO MA, WALO M, MANGIONE MR, BULONE D, DISPENZA C. Influence of gamma-irradiation on the thermally-induced mesoscopic gelation of degalactosylated xyloglucans. Radiat. Phys. Chem., 94 (2014) 245-248.
          France
          International scientific journal
          2014
          VO K. D. N., GUILLON E., DUPONT L., KOWANDY C., COQUERET X., Influence of Au(III) interactions with chitosan on gold nanoparticles formation, J. Phys Chem. (C) (2014), 118 (8), 4465–4474

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