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          Multiple Isotope Fingerprints to Identify Sources and Transport of Agro-Contaminants

          Closed for Proposals

          Project Type

          Coordinated Research Project

          Project Code

          D15018

          CRP

          2187

          Approved Date

          7 December 2017

          Project Status

          Closed

          Start Date

          12 April 2018

          Expected End Date

          31 December 2023

          Completed Date

          14 May 2024

          Participating Countries

          Austria, Australia, Switzerland, China, Germany, France, United Kingdom of Great Britain and Northern Ireland, Ghana, Ireland, India, Japan, Cambodia, Sri Lanka, Morocco, Romania, Slovenia, Viet Nam

          Description

          Pollution from agriculture and other sources has direct negative impacts on human health. A major knowledge gap regarding pollution in agro-ecosystems is source identification and apportionment, which requires more data, research and integration of approaches. When contamination from multiple sources to an agro-ecosystem occurs, traditional techniques cannot help in evaluating the relative contribution of the different sources. Complementarily to conventional monitoring and mass balance approaches, stable isotopes of major elements (H, C, N, O and S) have the potential to characterize and quantify sources and transport of solutes in agro-ecosystems. Studies have shown that depending on the origin of the polluting source, the isotopic signature of each element could be unique therefore it can be applied to fingerprint the source. This CRP aims to use stable isotopes of hydrogen, carbon, nitrogen, oxygen and sulphur as an integrated approach to identify and apportion sources and transport of agro-contaminants from soil to water bodies in agro-ecosystems.

          Objectives

          Identify and apportion macronutrient and micro-contaminant inputs in agro-ecosystems using an integrated isotope approach

          Specific Objectives

          Provide guidelines and decision trees for adapting and applying the toolbox

          Apply the combined approach to different agro-ecosystems to control contaminants

          Develop, evaluate and standardize an integrative isotope approach for identifying and apportioning sources of contaminants in agro-ecosystems

          Provide guidelines and decision trees for adapting and applying the toolbox

          Apply the combined approach to different agro-ecosystems to control contaminants

          Develop, evaluate and standardize an integrative isotope approach for identifying and apportioning sources of contaminants in agro-ecosystems

          Impact

          New analytical methods for source identification and apportion of phosphate (d18Op), sulphate (d34S-SO4, d18O-SO4) and pesticides (d13C and d15N), were developed and successfully tested in AUL, CPR, SLO, SRL, GHA, IND, SWI, and VIE, and are being transferred to member states through TC projects.

          Two regional (RAS5091 and RLA5089) and 3 National TC projects (BOL5024, COS7006, SLO5005) have applied the tools for isotopic water quality monitoring.

          The tools developed are also being applied to monitor the source and transport of agro-contaminants in transboundary Danube and Mekong collaboration with isotope hydrology laboratory (IHL), International Commission for the Protection of the Danube (ICPDR) and the Mekong River Commission.

          More than 100 publications illustrating the use of these isotopes to monitor soil and water quality in different agro-ecosystem.

          Fifteen young researchers completed MSc and PhD thesis related to this topic.

          Relevance

          The CRP has:
          (1) developed tools/guidelines/ SOPs for both field and laboratory work, already adapted by counterparts involved in both CRPs &TC projects.
          (2) provided background information for follow-up CRPs on oxygen isotopes of phosphate, sulfate, carbon and H2O isotopes to monitor water and sediment pollution in agroecosystem.
          (3) suggested land management strategies to mitigate and control agro-contaminants, however this remains the share responsibilities of the agro-chemical manufactures and policy makers in food and agriculture as well as the mining sectors

          CRP Publications

          Germany
          Journal Article (Environ. Sci. Technol)
          2020
          Dual-Element Isotope Analysis of Desphenylchloridazon to Investigate its Environmental Fate in a Systematic Field Study - A Long-Term Lysimeter Experiment
          UK
          Journal Article (Science of The Total Environment )
          2021
          'Evaluating the effectiveness of soil conservation at the basin scale using floodplain sedimentary archives
          Switzerland
          Journal Article (European Journal of Soil Science)
          2023
          Oxygen isotope ratios of phosphates in the soil-plant system: limitations and future developments
          India
          Journal Article
          2021
          Agricultural groundwater with high nitrates and dissolved salts given to pregnant mice alters brain development in the offspring
          Esat Africa
          Journal Article
          2021
          Building Climate Change Adaptation and Resilience through Soil Organic Carbon Restoration in Sub-Saharan Rural Communities: Challenges and Opportunities
          Austria/BOKU
          Journal Article
          2021
          New Ag3PO4 comparison material for stable oxygen isotope analysis
          UK
          Journal Article (Land Degradation and Development)
          2020
          Integrating land-water-people connectivity concepts across disciplines for co-design of soil erosion solutions
          China
          Journal Article( International Soil and Water Conservation Research)
          2023
          Novel sediment source fingerprinting quantifying erosion induced total nitrogen and total phosphorus outputs from an intensive agricultural catchment, North China
          China
          Journal Article (Journal of Environmental Radioactivity )
          2022
          Microscale spatial variability of Beryllium-7 at a reference site in southwest China
          Australia
          Journal Article (PlosONE17)
          2022
          FRAME -Monte Carlo model for evaluation of the stable isotope mixing and fractionation.
          Germany/Technical University of Munich
          Journal Article
          2023
          Leaching of four maize herbicides considering different processes
          Austria/IAEA
          Book
          2022
          Oxygen Isotopes of Inorganic Phosphate in Environmental Samples: Purification and Analysis
          Australia
          2023
          The measurement of ambient air moisture stable isotope composition for accurate estimation of evaporative losses
          Germany
          Journal Article
          2021
          Methodological advances to study contaminant biotransformation: new prospects for understanding and reducing environmental persistence?
          Vietnam
          Journal Article
          2021
          Tracing N-nutrient and organic carbon sources in surface water of Nhue River sub-catchment in Vietnam using stable isotope fingerprinting and related techniques.
          Austria/IAEA
          Book
          2024
          Tracing the Sources and Fate of Contaminants in Agroecosystems: Applications of Multi Stable Isotopes (Adu-Gyamfi et al.)
          UK
          Journal Article
          2020
          Integrating land-water-people connectivity concepts across disciplines for co-design of soil erosion solutions
          India
          Conference paper
          2022
          Transformation of pesticides in agricultural soil and groundwater: insights from pesticides and compound specific isotope analysis (CSIA) in the Berambadi catchment (South India)
          France
          Journal Article (MethodsX)
          2022
          Simplified protocols for sampling, sample preparation and analysis of pesticides using the compound-specific isotope analysis CSIA (d13C)
          China
          Journal Article
          2021
          Distribution of 137Cs and 60Co in plough layer of farmland: Evidenced from a lysimeter experiment using undisturbed soil columns
          Austria/IAEA
          Journal Article
          2022
          Nitrate sources and mixing in the Danube watershed: implications for transboundary river basin monitoring and management
          France
          Journal Article (Agriculture, Ecosystems & Environment )
          2020
          Plants affect the dissipation and leaching of anilide pesticides in soil mesocosms: Insights from compound-specific isotope analysis (CSIA)
          China
          EGU Conference proceeding
          2020
          The integrated use of stable isotopic and CSSI fingerprinting techniques to identify the sources of N pollutant in surface water and sediment in an agricultural catchment, North China
          UK
          Journal Article (Earth-Science Reviews)
          2022
          Understanding the complexity of sediment residence time in rivers: Application of Fallout Radionuclides (FRNs)
          Slovenia
          Journal Article (Agricultural water management)
          2022
          Effect of deficit irrigation on nitrogen accumulation and capsaicinoid content in Capsicum plants using the isotope 15N.
          Austria/IAEA
          Special Issue, Agriculture, Ecosystems & Environment Journal
          2021
          Agro-contaminants sources, transformation, and transport in agroecosystems (2021) was published in (Elsevier)
          Ghana/Ghana Atomic Energy Commission
          Journal Article (Environmental Pollution)
          2023
          Disentangling nitrate pollution sources and apportionment in a tropical agricultural ecosystem using a multi-stable isotope model.
          China
          Journal Article (Journal of Nuclear Agricultural Sciences)
          2020
          Response of Soil, Soil Carbon and Nitrogen Loss to Restoration Measures Under Event Based Rainfall in Erosion Degraded Forestland, Red Soil Region of China: Based on 7Be Tracing Technique
          Germany
          Journal Article (Environ. Science and Technology
          2021
          Triple-element compound-specific stable isotope analysis (3D-CSIA): added value of Cl isotope ratios to assess herbicide degradation.

          Contact CRP Officer

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