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          Radiation Curing of Composites for Enhancing their Features and Utility in Health Care and Industry

          Closed for proposals

          Project Type

          Coordinated Research Project

          Project Code

          F22051

          CRP

          1783

          Approved Date

          15 November 2010

          Status

          Closed

          Start Date

          14 March 2011

          Expected End Date

          14 March 2015

          Completed Date

          3 November 2015

          Description

          Composite materials combine properties of the individual components in a synergetic manner to produce a variety of materials in an efficient and cost effective manner. Thus, composite materials today are being used in various applications from sports equipment, automotive and aerospace industries to food packaging and artificial organs. Materials reinforced with nanoscale components are adding new dimensions to composite materials and enable further major improvements in functional and structural properties. The incorporation of only a few percent of nano-sized particles can make dramatic property changes that may result in sensing, actualization or self-healing properties of the resulting composite. Several major issues need to be addressed to utilize the full potential of such nanofillers, and among them: (i) incompatibility or weak interfacial bonding between the matrix and the nanoscale component, and (ii) agglomeration of nanosized component during processing resulting in inhomogeneous distribution. According to the results of ongoing investigation and products preparation in several Member States institutions, radiation technology offers a way of overcoming these challenges by grafting of appropriate monomers/polymers onto the nanofiller surface thereby fixing their morphology and at the same time making them compatible with the host polymer. Additionally, radiation techniques offer the possibility for simultaneous synthesis of the nanoparticle component and crosslinking of the matrix of the composite that is not possible to achieve by other techniques. With the availability of lower cost self-shielded low energy electron beam accelerators, this process is increasingly becoming available for developing member states. In order to use the advantages of radiation techniques and address the needs of Member States for producing advanced composite materials, this CRP has been formulated based on the recommendations of a Consultant’s Meeting. The CRP aims to support MS to develop methodologies and protocols for new abrasion resistant coating formulations, radiation curable nano-composites from natural polymers, new biodegradable packaging materials suitable for radiation sterilization, and new methods to modify surface characteristic of nano-sized materials to enhance polymer fillers interaction. This CRP will provide a forum for knowledge and technology transfer among the participating institutions, as well as to promote early involvement of developing countries in knowledge-intensive R&D programs to enhance their level of competence and confidence and promote the local spin-off initiatives.

          Objectives

          To enhance member States capability in the use of radiation technology for production of nano-composites with enhanced quality, safety, stability and functionality for advanced applications.

          Specific objectives

          To assess the methods to modify surface characteristic of nano-sized materials to enhance polymer fillers interaction

          To develop radiation curable nano-composites from natural polymers

          To harmonize preparations and specifications of new biodegradable packaging materials suitable for radiation sterilization

          To standardize formulations of new scratch and abrasion resistant coatings with enhanced surface finishing

          Impact

          The participants have developed numerous protocols for the preparation of nanocomposites that would not have been there without the joint effort under this CRP, and which are being transferred into new products. New preparation methods have been discovered that resulted in improved characteristics of the final products enabling new applications. Besides the collaboration towards the objectives of the CRP, strong collaboration and a network had been established that is in place and under a strategic partnership projects within the framework of EU Erasmus program is organizing and delivering training and teaching programme in enhancing development and transfer of knowledge of application of ionizing radiation in materials processing. The CRP also had an impact on the new CRP entitled: Application of Radiation Technology for the Development of Advanced Packaging Materials for Food Products", which benefits from the packaging materials developed under this completed CRP. Additionally, the journal articles published under this CRP enriched the knowledge of the scientific community worldwide.

          Relevance

          The CRP in line with the objective of the project 2.5.2.2, to enhance Member State capabilities in applying radiation technology for advanced materials development and processing natural polymers into value added products, and it is relevant to Member States programmes and projects.

          CRP Publications

          Type

          International scientific journal

          Year

          2012

          Description

          Khan, R., Salmieri, S., Dussault, D., Uribe-Calderon, J., Kamal, M.R., Safrany, A., Lacroix, M. Preparation, gamma-irradiation and thermo-mechanical characterization of chitosan loaded methylcellulose films. J. Polym. Environ. 20 (2012) 43-52

          Country/Organization

          Canada

          Type

          International scientific journal

          Year

          2011

          Description

          DUBEY, K. A., Y. K. BHARDWAJ, C. V. CHAUDHARI AND S. SABHARWAL, LDPE/EVA/PCR/MWNT nanocomposites: Radiation crosslinking and physicomechanical characteristics, Polymer Composites 32(5) (2011) 737-746

          Country/Organization

          India

          Type

          International scientific journal

          Year

          2014

          Description

          SALMIERI. S., ISLAM, F., KHAN, R. A., HOSSAIN, F. M., IBRAHIM, H. M. M., MIAO, C., HAMAD, W. Y., LACROIX, M., Antimicrobial nanocomposite films made of poly(lactic acid)-cellulose nanocrystals (PLA-CNC) in food applications. Part B: Effect of oregano essential oil release on the inactivation of Listeria monocytogenes in mixed vegetables. Cellulose. (2014) CELS-D-13-00484R2.

          Country/Organization

          Canada

          Type

          International scientific journal

          Year

          2010

          Description

          Khan, R., Salmieri, S., Dussault, D., Calderon, J.U., Kamal, M.R., Safrany, A., Lacroix, m. Production and Properties of Nanocellulose Reinforced Methylcellulose-Based Biodegradable Films. J. Agric. Food Chem., 58 (2010) 7878-7885

          Country/Organization

          Canada

          Type

          International scientific journal

          Year

          2014

          Description

          KRSTIC, J., SPASOJEVIC, J., RADOSAVLJEVIC, A., SILJEGOVIC, M., KACAREVIC-POPOVIC, Z., Optical and structural properties of radiolytically in situ synthesized silver nanoparticles stabilized by chitosan/poly(vinyl alcohol) blends, Rad. Phys. Chem. 96 (2014) 158-166.

          Country/Organization

          Serbia

          Type

          International scientific journal

          Year

          2014

          Description

          BAUER, F., DECKER, U., NAUMOV, S., RIEDEL, C. (2014). Photoinitiator-free UV curing and matting of acrylate-based nanocomposite coatings: Part 3. Progress in Organic Coatings 77 (2014) 1085-1094.

          Country/Organization

          Germany

          Type

          International scientific journal

          Year

          2012

          Description

          Khan, R., Dussault D., Salmieri, S., Safrany, A., Lacroix, M., Improvement of the mechanical and barrier properties of methylcellulose-based films by treatment with HEMA and silane monomers under gamma radiation. Rad. Phys. Chem., 81 (2012) 927-931.

          Country/Organization

          Canada

          Type

          International scientific journal

          Year

          2013

          Description

          Khan, R.A., Beck, S., Dussault, D., Salmieri, S., Bouchard, J., Lacroix, M. Mechanical and barrier properties of nanocrystalline cellulose reinforced poly (caprolactone) composites: effect of gamma radiation. J. Appl. Polymer Sc., 129 (2013) 3038-3046.

          Country/Organization

          Canada

          Type

          International scientific journal

          Year

          2012

          Description

          Huq, T., Khan, A., Dussault, D., Salmieri, S., Khan, R.A., Lacroix, M. Effect of ?-irradiation on the physico-chemical properties of alginate-based films and beads. Rad. Phys. Chem. 81 (2012) 945-48.

          Country/Organization

          Canada

          Type

          International scientific journal

          Year

          2014

          Description

          VO K. D. N., GUILLON E., DUPONT L., KOWANDY C., COQUERET X., Influence of Au(III) interactions with chitosan on gold nanoparticles formation, J. Phys Chem. (C) (2014), 118 (8), 4465–4474

          Country/Organization

          France

          Type

          International scientific journal

          Year

          2013

          Description

          NOWICKI A, G. PRZYBYTNIAK, K. MIRKOWSKI, “Radiacyjne sieciowanie zywic epoksydowych z napelniaczami nanoweglowymi” in ?Modyfikacja polimerów. Stan i perspektywy w roku 2013” Ed. Ryszarda Stellera i Danuty Zuchowskiej, Wroclaw 2013, TEMPO s.c., ISBN 978-83-85520-19-0, p. 382-385.

          Country/Organization

          Poland

          Type

          International scientific journal

          Year

          2010

          Description

          Senna M.M., Salmieri S, El-Naggar AW, Safrany A, Lacroix M. Improving the compatibility of Zein / Polyvinyl alcohol blends by gamma irradiation and graft copolymerization of acrylic acid. J. Agric. Food Chem., 58 (2010) 4470-4476.

          Country/Organization

          Canada/Egypt

          Type

          International scientific journal

          Year

          2012

          Description

          Sharmin, N., Khan, R., Dussault, D., Salmieri, S., Akter, N., Lacroix, M. Effectiveness of silane monomer and gamma radiation on chitosan films and PCL-based composites. Rad. Phys. Chem., 81 (2012) 932-935.

          Country/Organization

          Canada

          Type

          2012

          Year

          International scientific journal

          Description

          ALESSI S, SPINELLA A, CAPONETTI E, DISPENZA C, SPADARO G. Structural investigation of e-beam cured epoxy resins through solid state NMR. Radiat. Phys. Chem. 81 (2012) 1328-1331.

          Country/Organization

          Italy

          Type

          International scientific journal

          Year

          2013

          Description

          Khan, R. A., Beck, S., Dussault, D., Salmieri, S., Bouchard, J., Lacroix, M. Mechanical and barrier properties of carbon nanotubes-reinforced PCL-based composite films: effect of gamma radiation. J. Appl. Polym. Sci. 127 (2013) 3962-9.

          Country/Organization

          Canada

          Type

          International scientific journal

          Year

          2013

          Description

          YASIN, T., NISAR, M., SHAFIQ, M., NHO, Y.C., AHMAD, R. “Influence of Sepiolite and Electron Beam Irradiation on the Structural and Physicochemical Properties of Polyethylene/Starch Nanocomposites”. Polym. Composites, 34/3 (2013) 408–416.

          Country/Organization

          Pakistan

          Type

          International scientific journal

          Year

          2013

          Description

          NIK GHAZALI NIK SALLEH, MOHD SOFIAN ALIAS, H-J.GL?SEL & R.MEHNERT. High performance radiation curable hybrid coatings, Radiation Physics and Chemistry Journal, 84 (2013) 70-73.

          Country/Organization

          Malaysia/Germany

          Type

          International scientific journal

          Year

          2012

          Description

          DISPENZA C, SABATINO MA, NICONOV A, CHMIELEWSKA D, SPADARO G. E-beam crosslinked, biocompatible, functional hydrogels incorporating polyaniline nanoparticles. Radiat. Phys. Chem. 81 (2012) 1456-1459.

          Country/Organization

          Italy

          Type

          International scientific journal

          Year

          2014

          Description

          MAJJI, S., K. A. DUBEY, R. K. MONDAL, Y. K. BHARDWAJ AND S. ACHARYA, Development of Electron Beam Cross-Linked PDMS/PTFEM Composites with Low Coefficient of Friction and High Elastic Modulus, Polymer - Plastics Technology and Engineering 53(5) (2014) 435-441.

          Country/Organization

          india

          Type

          International scientific journal

          Year

          2013

          Description

          KARSLI, N.,G., AYTA?, A., AKBULUT, M., DENIZ, V., GüVEN,O., “Effect of irradiated polypropylene compatibilizer on the properties of short carbon fiber reinforced polypropylene composites” Rad. Phys. Chem.,84(2013)74-78

          Country/Organization

          Turkey

          Type

          International scientific journal

          Year

          2014

          Description

          KRSTIC, J., SPASOJEVIC, J., RADOSAVLJEVIC, A., PERIC-GRUJIC, A., DJURIC, M., KACAREVIC-POPOVIC, Z., POPOVIC, S., In vitro silver ion release kinetics from nanosilver/poly(vinyl alcohol) hydrogels synthesized by gamma irradiation, J. Appl. Polym. Sci. 131 (2014) Article No. 40321.

          Country/Organization

          Serbia

          Type

          International scientific journal

          Year

          2014

          Description

          FARAHANI,.M., CLOCHARD, M.C., GIFFORD, I., BARKATT, A. AND AL-SHEIKHLY, M., Differences in Fundamental Reaction Mechanisms between High and Low-LET in Recent Advancements and Applications of Ionizing Radiation, Rad. Phys. Chem., 105 (2014) 39–47.

          Country/Organization

          USA/France

          Type

          International scientific journal

          Year

          2013

          Description

          SINHA, S. K., K. A. DUBEY, V. GROVER, P. SASTRY, Y. K. BHARDWAJ, L. PANICKER, A. K. TYAGI, P. A. MAHANWAR AND V. A. BAMBOLE, Selective interfacial localization in conducting polycaprolactam/ethylene vinyl acetate/carbon black composites, Polymer Composites 34(6) (2013) 912-919.

          Country/Organization

          India

          Type

          International scientific journal

          Year

          2014

          Description

          Lacroix, M., Khan, R., Senna, M., Sharmin, N., Salmieri, S., SAFRANY, A, Radiation grafting on natural films. Rad. Phys. Chem., 94 (2014) 88-92.

          Country/Organization

          Canada

          Type

          International scientific journal

          Year

          2012

          Description

          BAKAR, A., DE, V.V., ZEZIN, A.A., ABRAMCHUK, S.S., GüVEN,O., FELDMAN,V.I., “Spatial organization of a metal-polymer nanocomposite obtained by radiation-induced reduction of copper ions in the poly(allyl amin)-poly(acrylic acid)-Cu2+ system” Mendeleev Commun., 22(2012)211.

          Country/Organization

          Turkey

          Type

          International scientific journal

          Year

          2014

          Description

          VO K. D. N., KOWANDY C., DUPONT L., NGUYEN Q. H., COQUERET X., Radiation synthesis of chitosan-stabilized gold nanoparticles: comparison between e(-) beam and gamma irradiation, Radiat. Phys. Chem. (2014), 94, 84-87

          Country/Organization

          France/Vietnam

          Type

          International scientific journal

          Year

          2014

          Description

          BAKAR, A., GüVEN,O., ZEZIN, A.A., FELDMAN,V.I., “Controlling the size and distribution of copper nanoparticles in double and triple polymer-metal complexes by X-ray irradiation” Rad. Phys. Chem.,94(2014)62-65.

          Country/Organization

          Turkey

          Type

          International scientific journal

          Year

          2013

          Description

          KHAN, A., MEHMOOD, S., SHAFIQ, M., YASIN, T., AKHTER, Z., AHMAD, S. “Structural and Antimicrobial Properties of Irradiated Chitosan and its Complexes with Zinc”. Radiat Phys Chem, 91 (2013) 138–142

          Country/Organization

          Pakistan

          Type

          International scientific journal

          Year

          2012

          Description

          DUBEY, K. A., Y. K. BHARDWAJ, K. RAJKUMAR, L. PANICKER, C. V. CHAUDHARI, S. K. CHAKRABORTY AND S. SABHARWAL, Polychloroprene rubber/ethylene-propylene diene monomer/multiple walled carbon nanotube nanocomposites: Synergistic effects of radiation crosslinking and MWNT addition, Journal of Polymer Research 19(5)(2012).

          Country/Organization

          India

          Type

          International scientific journal

          Year

          2012

          Description

          Sharmin, N., Khan, R., Salmieri, S., Dussault, D., Bouchard, J., Lacroix, M. Mechanical and barrier properties of methylcellulose-based films grafted with trimethylolpropane trimethacrylate by gamma irradiation: effect of filling with cellulose nanocrystals, J. Sc. Technol. For Forest Products and Processes 2 (2012) 24-31.

          Country/Organization

          Canada

          Type

          International scientific journal

          Year

          2011

          Description

          NIK GHAZALI NIK SALLEH, MOHD FIRDAUS YHAYA, AZMAN HASSAN, AZNIZAM ABU BAKAR AND MUNIRAH MOKHTAR, Effect of radiation dosages on the properties of nanocomposite coatings. Radiation Physics and Chemistry Journal 80 (2011) 136-141.

          Country/Organization

          Malaysia

          Type

          International scientific journal

          Year

          2012

          Description

          Khan, A., Huq, T., Khan, R.A., Dussault, D., Salmieri, S., Lacorix, M. Effect of ?-irradiation on the mechanical and barrier properties of HEMA grafted chitosan-based films. Rad. Phys. Chem., 81 (2012) 941-44.

          Country/Organization

          Canada

          Type

          International scientific journal

          Year

          2014

          Description

          SPADARO G, ALESSI S, DISPENZA C, SABATINO MA, PITARRESI G, TUMINO D, PRYZBYTNIAK G, Radiation curing of carbon fibre composites. Radiat. Phys. Chem. 94 (2014) 14-17.

          Country/Organization

          Italy/Poland

          Type

          International scientific journal

          Year

          2011

          Description

          DUBEY, K. A., Y. K. BHARDWAJ, C. V. CHAUDHARI, N. K. GOEL, S. SABHARWAL, K. RAJKUMAR AND S. K. CHAKRABORTY, Radiation effects on styrene-butadiene-ethylene-propylene diene monomer-multiple walled carbon nanotube nanocomposites: Vulcanization and characterization, Polymers for Advanced Technologies, 22(12)(2011)1888-1897.

          Country/Organization

          India

          Type

          International scientific journal

          Year

          2014

          Description

          TODARO S, SABATINO MA, WALO M, MANGIONE MR, BULONE D, DISPENZA C. Influence of gamma-irradiation on the thermally-induced mesoscopic gelation of degalactosylated xyloglucans. Radiat. Phys. Chem., 94 (2014) 245-248.

          Country/Organization

          Italy/Poland

          Type

          International scientific journal

          Year

          2012

          Description

          Akter, N., Khan, R., Salmieri, S., Sharmin, N., Dussault, D., Lacroix, M. Fabrication and mechanical characterization of biodegradable and synthetic polymeric films: Effect of ?-irradiation. Rad. Phys. Chem., 81 (2012) 995-998.

          Country/Organization

          Canada

          Type

          International scientific journal

          Year

          2014

          Description

          DUBEY, K. A., S. K. SINHA, Y. K. BHARDWAJ, L. PANICKER AND L. VARSHNEY, Carbon Black-Filled PE/PP/EPDM Blends: Phase Selective Localization of Carbon Black and EPDM-Induced Phase Stabilization." Polymer - Plastics Technology and Engineering 53(5) (2014) 442-450.

          Country/Organization

          India

          Type

          International scientific journal

          Year

          2014

          Description

          CHAUDHARI, C. V., K. A. DUBEY, Y. K. BHARDWAJ AND S. SABHARWAL, Radiation processed styrene-butadiene rubber/ethylene-propylene diene rubber/multiple-walled carbon nanotubes nanocomposites: Effect of MWNT addition on solvent permeability behavior, Journal of Macromolecular Science, Part B: Physics 51(5)(2014) 839-859

          Country/Organization

          India

          Type

          International scientific journal

          Year

          2013

          Description

          QUOC, L.A, PHU, D.V, DUY, N.N, LANG, V.T.K, LAN, N.T.K., TRINH, N.T.A., HIEN, N.Q., Study on antibacterial activity (Escherichia coli) of porous ceramic fixed with silver nanoparticles, Nuclear Science and Technology, VINATOM, 3 (2013) 25-30.

          Country/Organization

          Vietnam

          Type

          International scientific journal

          Year

          2012

          Description

          Sharmin, N., Khan, R.A., Salmieri, S., Dussault, D., Bouchard, J., Lacroix, M. Modification and characterization of biodegradable methylcellulose films with trimethylolpropane trimethacrylate (TMPTMA) by gamma radiation: effect of nanocrystalline cellulose. J. Agric. Food Chem., 60 (2012) 623-629.

          Country/Organization

          Canada

          Type

          International scientific journal

          Year

          2013

          Description

          PHU, D.V., TRINH, N.T.A., DU, B.D., HIEN, N.Q., Gamma-irradiation synthesis of silver nanoparticles fixing in porous ceramic for application in water treatment, Vietnam Journal of Chemistry, 51 (2013) 653-657.

          Country/Organization

          Vietnam

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