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          Development of Radiation-Processed Products of Natural Polymers for Application in Agriculture, Healthcare, Industry and Environment

          Closed for proposals

          Project Type

          Coordinated Research Project

          Project Code

          F22046

          CRP

          1467

          Approved Date

          19 September 2007

          Status

          Closed

          Start Date

          1 December 2007

          Expected End Date

          31 December 2012

          Completed Date

          13 January 2013

          Description

          Radiation processing offers a clean and additive-free method for preparation of value-added novel materials based on renewable, non-toxic and biodegradable natural polymers. The results of research work in some Member States showed that natural polysaccharides (alginate, chitin/chitosan, carrageeneans) could be either crosslinked or degraded (reduced molecular weight) by radiation. The crosslinked products can be used as hydrogel wound dressings, face cleaning cosmetic masks, adsorbents of toxins and non-bedsore mats. The low molecular weight products show antibiotic, antioxidant and plant-growth promoting properties. This CRP will focus on identification of methodologies and QA protocols for investigating structure-property relationship particularly with respect to radiation induced changes in natural polymers, investigating the anti-oxidant properties of low molecular weight natural polymers and assessing suitability for preservation of food and allied products and field-testing the potential of radiation-modified polysaccharides as plant growth promoters, soil conditioners and for enhancing fermentation of agro by-products

          Objectives

          The overall objective of the proposed research project was the wide-spread promotion and general application of radiation processed natural materials, coupling radiation technology and end-users to derive enhanced benefits from these value-added natural materials.

          Specific objectives

          Field-testing the potential of radiation-modified polysaccharides as plant growth promoters, soil conditioners and for enhancing fermentation of agro by-products.

          Identification of methodologies and QA protocols for investigating structure-property relationship particularly with respect to radiation induced changes in natural polymers.

          Investigating the anti-oxidant properties of low molecular weight natural polymers and assessing suitability for preservation of food and allied products.

          Impact

          The CRP had very high impact on enhancing the research capabilities of the participating institutions in applying radiation techniques to convert indigenous, non-toxic and renewable natural polymers into value added and marketable products. Under this CRP several institutions succeeded in starting the production of radiation-processed polysaccharides, the participants developed and successfully applied protocols for characterization of obtained low molecular weight polymers, as well as obtained good results in applying these products as plant growth promoters, soil conditioners and plant protectors in green house and field trials. The participants established numerous collaborations and signed relevant agreements between their institutions that will be in effect long after this CRP is completed. Participants has also used additional Agency support under national and regional TC project to collaborate, and had also applied jointly for additional support of their work at various EU institutions.

          Relevance

          The CRP is in line with research and development priorities of participating MS, and they expressed strong interest and commitment for continued work and collaboration.

          CRP Publications

          Type

          scientific meeting contribution

          Year

          2012

          Description

          ARANILLA, C.T., NAGASAWA, N., BAYQUEN, A., DELA ROSA, A., Synthesis and Characterization of Carboxymethyl Derivatives of Kappa-Carrageenan, Carbohydrate Polymers 87 (2012) 1810.

          Country/Organization

          Philippines and Japan

          Type

          scientific paper

          Year

          2009

          Description

          L.V. ABAD, H. KUDO, S. SAIKI, N. NAGASAWA, M. TAMADA, Y. KATSUMURA, C.T. ARANILLA, L.S. RELLEVE AND A.M. DE LA ROSA, 2009. Radiation degradation studies of carrageenans. Carbohyd. Polym. 78, 100-106.

          Country/Organization

          Philippines and Japan

          Type

          scientific paper

          Year

          2011

          Description

          P. N. TAKALA, D. K. VU, S. SALMIERI, AND M. LACROIX 2011 Effect of Antimicrobial Coatings on the Radiosensitization of Escherichia coli, Salmonella Typhimurium, and Listeria monocytogenes in Fresh Broccoli., J. Food Protection

          Country/Organization

          Canada

          Type

          scientific paper

          Year

          2008

          Description

          SAIKI, S, MUROYA, Y., KUDO, H., KATSUMURA, Y., NAGASAWA, N., YOSHII, Y., Pulse Radiolysis Study on Aqueous Solutions of Polysaccharide Derivatives. ACS Symp. Ser. 978 (2008) 166.

          Country/Organization

          Japan

          Type

          scientific paper

          Year

          2011

          Description

          MONDOL, M.M.A., RANA, M.I.K., DAFADER, N.C., HAQUE, M.E., Effect of foliar application of chitosan on growth and yield in Indian Spinach. J. Agrofor. Environ. 5 (2011) 99-102.

          Country/Organization

          Bangladesh

          Type

          scientific paper

          Year

          2010

          Description

          SAIKI, S., NAGASAWA, N., HIROKI, A., MORISHITA, N., TAMADA, M., MUROYA, Y., KUDO, H., KATSUMURA, Y., ESR Study on Carboxymethyl Chitosan Radicals in an Aqueous Solution. Radiat. Phys. Chem. 79 (2010) 276.

          Country/Organization

          Japan

          Type

          scientific meeting contribution

          Year

          2011

          Description

          CLOZZA,M., CAVAGLIA,A., GARCIA KVASINA,S., DIVO de SESAR,M.D., SMOLKO,E.E. "Influencia de la Aplicación de Alginatos Irradiados sobre el Crecimiento de Especies Hortícolas". XXXIV Argentine Horticultura Congress , Buenos Aires, September 27(2011).

          Country/Organization

          Argentina

          Type

          scientific paper

          Year

          2009

          Description

          KASAHARA, T., TAKIGAMI, M., NAGASAWA, N., TAKIGAMI, S., Effect of KM Molar Mass on CMC-KM-acid Gel. Trans. Mater. Res. Soc. Jpn. 34 (2009) 395.

          Country/Organization

          Japan

          Type

          scientific paper

          Year

          2012

          Description

          OKUBO, S., NAGASAWA, N., KOBAYASHI, A., GOWA OYAMA, T., TAGUCHI, M., OSHIMA, A., TAGAWA, S., WASHIO, M., Micro-/Nanofabrication of Cross-linked Poly(L-lactic acid) Using Electron Beam Nanoimprint Lithography. Applied Physics Express 5 (2012) 027303.

          Country/Organization

          Japan

          Type

          scientific paper

          Year

          2011

          Description

          HIROKI, A., HONG, P.T.T., NAGASAWA, N., TAMADA, M., Biodegradability of Blend Hydrogels Based on Carboxymethyl Cellulose and Carboxymethyl Starch, Trans. Mater. Res. Soc. Jpn. 36 (2011) 397.

          Country/Organization

          Japan

          Type

          Chapter

          Year

          2011

          Publication URL

          http://www.intechweb.org

          Description

          GULREZ, S, AL-ASSAF, S., PHILLIPS, G.O., Hydrogels: Methods of preparation, characterization and applications, in "Bioengineering" , InTech - Open Access Publisher, ISBN 978-953-307-268-52011

          Country/Organization

          UK

          Type

          scientific paper

          Year

          2012

          Description

          Nacer Khodja A, Mahlous M, Tahtat D, Benamer S, Larbi Youcef S, Chader H, Mouhoub L, Sedgelmaci M, Ammi N, Mansouri M B, Mameri S. (2012) Evaluation of healing activity of PVA/chitosan hydrogels on deep second degree burn: pharmacological and toxicological tests. Burns (in press)

          Country/Organization

          Algeria

          Type

          scientific paper

          Year

          2013

          Description

          DUARTE, C.L. Ribeiro, M. A., Oikawa H, Mori, M. N., Napolitano, C.M., Galv?o, C.A., Study of thermal treatment combined with radiation on the decomposition of polysaccharides in sugarcane bagasse, Radiat. Phys. Chem. 84 (2013) 191.

          Country/Organization

          Brazil

          Type

          scientific paper

          Year

          2012

          Description

          CZECHOWSKA-BISKUP, R., JAROSINSKA, D., ROKITA, B., ULANSKI, P., ROSIAK, J.M., “Determination of degree of deacetylation of chitosan - comparison of methods”, Progress on Chemistry and Application of Chitin and its Derivatives", vol. XVII, (JAWORSKA, M., Ed.), ISBN 83-918969-5-1, Polish Chitin Society, Lodz (in press).

          Country/Organization

          Poland

          Type

          scientific paper

          Year

          2010

          Description

          ABAD, L.V., KUDO, H., SAIKI, S., NAGASAWA, N., TAMADA, M., FU, H., MUROYA, Y., LIN, M., KATSUMURA, Y., RELLEVE, L.S., AEANILLA, C.T., DELA ROSA, A.M., Radiolysis Studies of Aqueous ?-Carrageenan. Nucl. Instr. and Meth. in Phys. Res. B. 268 10 (2010) 1607.

          Country/Organization

          Philippines and Japan

          Type

          scientific paper

          Year

          2011

          Description

          OCLOO, F.C.K., QUAYSON, E.T., ADU-GYAMFI, A., QUARCOO, E.A., ASARE, D., SERFOR-ARMAH, Y. and WOODE, B. K. (2011). Physico-chemical and functional characteristics of radiation processed shrimp chitosan. Radiation Physics and Chemistry 80 (7). Pp. 837-841.

          Country/Organization

          Ghana

          Type

          scientific paper

          Year

          2012

          Description

          OCLOO, F.C.K., ADU-GYAMFI, A., QUARCOO, E. A., SERFOR-ARMAH, Y., ASARE, D. K. and OWULAH, C. (Accepted, 2012). Effect of gamma irradiation on antibacterial properties of sea crab shell chitosan. European Journal of Food Research and Review

          Country/Organization

          Ghana

          Type

          scientific meeting contribution

          Year

          2011

          Description

          CZECHOWSKA-BISKUP, R., ROSIAK, J.M., ULANSKI, P., “Determination of average molecular weight and radiation-chemical degradation yield of chitosan - an interlaboratory study”, XVIIth Workshop "New aspect on chemistry and application of chitin and its derivatives", Warsaw, September 21-23, 2011.

          Country/Organization

          Poland

          Type

          scientific meeting contribution

          Year

          2011

          Description

          CZECHOWSKA-BISKUP R., JAROSINSKA, D., ULANSKI, P., ROSIAK, J.M., “Determination of degree of deacetylation of chitosan - comparison of methods”, XVIIth Workshop "New aspect on chemistry and application of chitin and its derivatives", Warsaw, September 21-23, 2011.

          Country/Organization

          Poland

          Type

          scientific paper

          Year

          2011

          Description

          TAHTAT, D., MAHLOUS, M., BENAMER, S., NACER KHODJA, A., LARBI YOUCEF, S., HADJARAB, N., MEZAACHE, W. (2011). Influence of some factors affecting antibacterial activity of PVA/Chitosan based hydrogels synthesized by gamma irradiation. Journal of Materials Science: Materials in Medicine. 22: 2505–2512

          Country/Organization

          Algeria

          Type

          scientific paper

          Year

          2012

          Description

          OCLOO, F.C.K., ADU-GYAMFI, A., QUARCOO, E. A., SERFOR-ARMAH, Y. and ASARE, D. (2012). Antifungal properties of gamma-irradiated chitosan from sea crab shells. International Journal of Recent Trends in Science and Technology. ISSN 2277-2812 E-ISSN 2249-8109, Volume 3, Issue 3. pp 82-84

          Country/Organization

          Ghana

          Type

          scientific meeting contribution

          Year

          2009

          Description

          NABINGER,P., CERCHIETTI,M.L., MONDINO,A., SMOLKO.E.E. "Control de la Radiodegradacion de Polímeros Naturales Mediante la Determinación del Peso Molecular por Medición de Viscocidad". Proceedings of the XXXVI Annual Meeting of the Argentine Nuclear Technology Association (AATN 2009), Buenos Aires, 16-20 November(2009)

          Country/Organization

          Argentina

          Type

          scientific paper

          Year

          2008

          Description

          ZHAO, L., LUO, F., WASIKIEWICZ, J.M., MITOMO, H., NAGASAWA, N., YAGI, T., TAMADA, M., YOSHII, F., Adsorption of Humic Acid from Aqueous Solution onto Irradiation-crosslinked Carboxymethyl Chitosan. Bioresour. Technol. 99 (2008) 1911.

          Country/Organization

          Japan

          Type

          scientific paper

          Year

          2011

          Description

          NAGASAWA, N., KASAI, N., YAGI, T., YOSHII, F., TAMADA, M., Radiation-induced Crosslinking and Post-processing of Poly(L-lactic acid) Composite. Radiat. Phys. Chem. 80 (2011) 145.

          Country/Organization

          Japan

          Type

          scientific paper

          Year

          2011

          Description

          L.V. ABAD, S.SAIKI, N. NAGASAWA, H. KUDO, Y. KATSUMURA, AND A. M. DE LA ROSA, 2011. NMR analysis of fractionated irradiated k-carrageenan oligomers as plant growth promoter. Radiation Physics and Chemistry. 80, 977–982.

          Country/Organization

          Philippines and Japan

          Type

          scientific paper

          Year

          2008

          Description

          KUMARA, S, NAGASAWA, N., YAGI, T., TAMADA, M., Radiation-induced Crosslinking and Mechanical Properties of Blends of Poly(lactic acid) and Poly(butylene terephthalate-co-adipate). J. Appl. Polym. Sci. 109 (2008) 3321.

          Country/Organization

          Japan

          Type

          scientific paper

          Year

          2011

          Description

          SAIKI, S., NAGASAWA, N., HIROKI, A., MORISHITA, N., TAMADA, M., KUDO, H., KATSUMURA, Y., ESR Study on Radiation-induced Radicals in Carboxymethyl Cellulose Aqueous Solution. Radiat. Phys. Chem. 80 (2011) 149.

          Country/Organization

          Japan

          Type

          scientific paper

          Year

          2012

          Description

          DUARTE, C.L. Ribeiro, M. A., Oikawa H, Mori, M. N., Napolitano, C.M., Galv?o, C.A., Electron beam combined with hydrothermal treatment for enhancing the enzymatic convertibility of sugarcane bagasse, Radiat. Phys. Chem. 81 (2012) 1008.

          Country/Organization

          Brazil

          Type

          scientific paper

          Year

          2009

          Description

          LUAN, L.Q., NAGASAWA, N., HA, V.T.T., NAKANISHI, T.M., A Study of Degradation Mechanism of Alginate by Gamma-irradiation. Radioisotopes 58 (2009) 3.

          Country/Organization

          Japan

          Type

          scientific paper

          Year

          2010

          Description

          EL-SAWY, N.M. ABD EL-REHIM, H.A. ELBARBARY, A.M., HEGAZY E.A. (2010): Radiation-induced degradation of chitosan for possible use as a growth promoter in agricultural purposes. Carbohyd. Polym. 79: 555-562.

          Country/Organization

          Egypt

          Type

          scientific paper

          Year

          2012

          Description

          RUHUL A. KHAN, STEPHANE SALMIERI, DOMINIC DUSSAULT, NATHALIE TUFENKJI, JORGE URIBE-CALDERON, MUSA R. KAMAL, AGNES SAFRANY AND MONIQUE LACROIX 2012, Preparation and Thermo-mechanical Characterization of Chitosan Loaded Methylcellulose-based Biodegradable Films: Effects of Gamma Radiation. J. Polym Environ (2012) 20:43-52

          Country/Organization

          Bangladesh and Canada

          Type

          scientific paper

          Year

          2011

          Description

          N.N. DUY, D.V. PHU, N.T. ANH, N.Q. HIEN, Synergistic degradation to prepare oligochitosan by g-irradiation of chitosan solution in the presence of hydrogen peroxide, Radiation Physics and Chemistry, 80 (2011) 848-853.

          Country/Organization

          Vietnam

          Type

          scientific paper

          Year

          2009

          Description

          LUAN, L.Q., NAGASAWA, N., HA, V.T.T., HIEN, N.Q., NAKANISHI, T.M., Enhancement of Plant Growth Stimulation Activity of Irradiated Alginate by Fractionation. Radiat. Phys. Chem. 78 (2009) 796.

          Country/Organization

          Japan

          Type

          scientific paper

          Year

          2009

          Description

          HIROKI, A., TRAN, H.T., NAGASAWA, N., YAGI, T., TAMADA, M., Metal Adsorption of Carboxymethyl Cellulose / Carboxymethyl Chitosan Blend Hydrogels Prepared by Gamma Irradiation. Radiat. Phys. Chem. 78 (2009) 1076.

          Country/Organization

          Japan

          Type

          scientific paper

          Year

          2008

          Description

          KASAHARA, T., TAKIGAMI, M., NAGASAWA, N., PRAWITWONG, P., TAKIGAMI, S., Preparation and Characterization of CMC-Konjac Mannan Mixture Gel. Trans. Mater. Res. Soc. Jpn. 33 (2008) 927.

          Country/Organization

          Japan

          Type

          scientific paper

          Year

          2010

          Description

          OKUBO, S., TAKAHASHI, T., GOWA, T., SASAKI, T., NAGASAWA, N., TAMADA, M., OSHIMA, A., TAGAWA, S., WASHIO, M., Micro-fabrication of Biodegradable Polymers Using Focused Ion Beam. Journal of Photopolymer Science and Technology 23 (2010) 393.

          Country/Organization

          Japan

          Type

          scientific paper

          Year

          2010

          Description

          RUHUL A.KHAN, STEPHANE SALMIERI, DOMINICDUSSAULT, JORGEURIBE-CALDERON, MUSA R. KAMAL, AGNES SAFRANY AND MONIQUE LACROIX 2010 Production and Properties of Nanocellulose-ReinforcedMethylcellulose-Based Biodegradable Films. J. Agric. Food Chem. 58, 7878-7885.

          Country/Organization

          Bangladesh and Canada

          Type

          scientific meeting contribution

          Year

          2009

          Description

          CERCHIETTI,M.L., GIARDINA,E.B., VILLELA,F., DIVO,M.D., CLOZZA,M., SMOLKO,E.E. "Polisacaridos Irradiados para su Aplicación en Agricultura: Resultados preliminares". Proceedings of the XXXVI Annual Meeting of the Argentine Nuclear Technology Association (AATN 2009), Buenos Aires, 16-20 November(2009).

          Country/Organization

          Argentina

          Type

          scientific paper

          Year

          2008

          Description

          TAKIGAMI, M., AMADA, H., NAGASAWA, N., HIROKI, A., KASAI, N., YOSHII, F., TAMADA, M., Adsorption Phosphate Ion in Swine Urine Using CMC Gel. Trans. Mater. Res. Soc. Jpn. 33 (2008) 849.

          Country/Organization

          Japan

          Type

          scientific paper

          Year

          2010

          Description

          L.V. ABAD, H. KUDO, S. SAIKI, N. NAGASAWA, M. TAMADA, H. FU, Y. MUROYA, M. LIN, Y. KATSUMURA, L.S. RELLEVE, C.T. ARANILLA, AND A.M. DELA ROSA, 2010. Radiolysis studies of aqueous ?-carrageenan. Nucl. Instr. Meth. Phys.Res. B. 268, 1607–1612.

          Country/Organization

          Philippines and Japan

          Type

          scientific paper

          Year

          2011

          Description

          ABAD, L.V., SAIKI, S., NAGASAWA, N., KUDO, H., KATSUMURA, Y., DELA ROSA, A.M., NMR Analysis of Fractionated Irradiated k-Carrageenan Oligomers as Plant Growth Promoter. Radiat. Phys. Chem. 80 (2011) 977.

          Country/Organization

          Philippines and Japan

          Type

          scientific paper

          Year

          2011

          Description

          Khairul Zaman, C.T. Ratnam, Jamaliah Sharif, Dahlan Hj Mohd, Mahathir Mohamed and Kamaruddin Hashim, Radiation processing of natural polymer for industrial and healthcare applications in Malaysia, Journal of Radiation & Industries (Japan), Series No. 130 (2011) 10-14.

          Country/Organization

          Malaysia

          Type

          Book chapter

          Year

          2010

          Description

          GULREZ, S, AL-ASSAF, S., PHILLIPS, G.O., Characterization and Radiation Modification of Carrageenan in the Solid State, in "Radiation Processing Technology Applications", Khandal, RK, Niyogi, U.Uk., Eds. SRI Publication, 1st Edition, pp 519-532

          Country/Organization

          UK

          Type

          scientific meeting contribution

          Year

          2011

          Description

          Norzita Yacob, Maznah Mahmod, Norhashidah Talip, Mohd Yusof Hamzah & Kamaruddin Hashim, The degradation of chitosan by radiation: Effect on physicochemical property, the 24th Regional Symposium Analytical Sciences (SKAM), 21-23 Nov 2011, One Hotel Helang, Langkawi.

          Country/Organization

          Malaysia

          Type

          scientific paper

          Year

          2012

          Description

          N.Q. HIEN, D.V. PHU, N.N. DUY, N.T.K. LAN, Degradation of chitosan in solution by gamma irradiation in the presence of hydrogen peroxide, Carbohydrate Polymers, 87 (2012) 935-938.

          Country/Organization

          Vietnam

          Type

          scientific meeting contribution

          Year

          2012

          Description

          Norzita Yacob, Maznah Mahmud, Norhashidah Talip, Kamaruddin Hashim, Abdul Rahim Harun, Khairul Zaman Hj Dahlan, Chemical Radiation Degradation of Chitosan for Rice Crops Application, The 4th Asia-Pacific Symposium on Radiation Chemistry (APSRC-2012), Huangshan, China: 30 Oct. - 3 Nov. 2012.

          Country/Organization

          Malaysia

          Type

          scientific paper

          Year

          2010

          Description

          MAGDY M. SENNA, STEPHANE SALMIERI, ABDEL-WAHAB EL-NAGGAR,AGNES SAFRANY, AND MONIQUE LACROIX 2010 Improving the Compatibility of Zein/Poly(vinyl alcohol) Blends byGammaIrradiation and GraftCopolymerization ofAcrylicAcid J. Agric. Food Chem. 58, 4470-4476.

          Country/Organization

          Canada and Egypt

          Type

          scientific paper

          Year

          2010

          Description

          VANICHVATTANADECHA, C., SUPAPHOL, P., NAGASAWA, N., TAMADA, M., TOKURA, S., FURUIKE, T., TAMURA, H., RUJIRAVANIT, R., Effect of Gamma Radiation on Dilute Aqueous Solutions and Thin Films of N-succinyl Chitosan. Polymer Degradation and Stability 95 2 (2010) 234.

          Country/Organization

          Thailand and Japan

          Type

          scientific paper

          Year

          2010

          Description

          SEN, M., RENDEVSKI, S., AKKAS KAVAKLI, P., SEPEHRIANAZAR, A., Effect of G/M ratio on the radiation-induced degradation of sodium alginate. Radiation Physics and Chemistry, 79(2010) 279–282.

          Country/Organization

          Turkey

          Type

          scientific paper

          Year

          2009

          Description

          TAKIGAMI, M., HIROKI, A., NAGASAWA, N., KASAHARA, T., TAKIGAMI, S., TAMADA, M., Effect of CMC Molar Mass on Mechanical Properties of CMC-acid Gel. Trans. Mater. Res. Soc. Jpn. 34 (2009) 391.

          Country/Organization

          Japan

          Type

          scientific paper

          Year

          2012

          Description

          Tahtat, D., Mahlous, M., Benamer, S., Nacer Khodja, A., Larbi Youcef, S. (2012) Effect of molecular weight on radiation chemical degradation yield of chain scission of ? irradiated chitosane in solid state and in aqueous solution. Radiation Physics and Chemistry. 81 659–665.

          Country/Organization

          Algeria

          Type

          scientific paper

          Year

          2011

          Description

          ABD EL-REHIM H.A., EL-SAWY, N.M., FARAG I.A., ELBARBARY, A.M. Synergistic effect of combining ionizing radiation and oxidizing agents on controlling degradation of Na-alginate for enhancing growth performance and increasing productivity of Zea maize plants, Carbohyd. Polym. (2011)

          Country/Organization

          Egypt

          Type

          scientific paper

          Year

          2008

          Description

          L.V. ABAD , S. OKABE, M. SHIBAYAMA, H. KUDO, S. SAIKI, C. ARANILLA, L. RELLEVE, AND A.M. DE LA ROSA, 2008. Comparative studies on the conformational change and aggregation behavior of irradiated carrageenans and agar by dynamic light scattering. Int. J. Biol. Macromol, 42, 55-61.

          Country/Organization

          Philippines and Japan

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